\begin{table}%T2 \caption{\label{tab:1514h}Rotational transition frequencies and spectroscopic constants of $^{15}$NNH$^+$.} \small%\centerline { \begin{tabular}{ccccc} \hline\hline \noalign{\smallskip} $J'$ & $J$ & {Observed} & {Obs.-calc.} & {Uncert.$^{{a}}$} \\ & & {(MHz)} & {(kHz)} & {(kHz)} \\ \hline \noalign{\smallskip} 1 & 0 & 90~263.8330$^{{b}}$ & --2.3 & 10. \\ 3 & 2 & 270~783.5870 & 8.1 & 20. \\ 4 & 3 & 361~035.5242 & 0.7 & 5. \\ 5 & 4 & 451~279.5385 & --2.4 & 5. \\ 6 & 5 & 541~513.6509 & 1.5 & 5. \\ 7 & 6 & 631~735.8673 & 0.2 & 5. \\ 8 & 7 & 721~944.2091 & --3.1 & 15. \\\noalign{\smallskip} \mcl{5}{l}{rms$_{\rm res}$$^{{c}} = 3.6$~kHz}\\ \mcl{5}{l}{$\sigma^{d} = 0.350$} \\ \hline \mcl{2}{l}{Constant$^{{e}}$} & & \mcl{2}{r}{Correlation matrix} \\ \hline \mcl{2}{l}{$B_0$ / MHz} & 45~132.08283(23) & 1.000 \\ \mcl{2}{l}{$D_J$ / kHz} & 82.5747(28) & --0.943 & 1.000 \\ \hline \end{tabular}} \smallskip $^{{a}}$ Uncertainties estimated as explained in the text.\\ $^{{b}}$ From \citet{Gudeman-PhDTh82}.\\ $^{{c}}$ Rms error of residuals: $\sqrt{\frac{\sum {\rm residual}^2}{{N\;{\rm observations}}}}$.\\ $^{{d}}$ Fit standard deviation: $\sqrt{\frac{\sum {\rm (residual/uncert.)}^2}{{\rm degrees\;of\;freedom}}}$.\\ $^{{e}}$ Standard errors are reported in parentheses in units of the last quoted digits. \end{table}