\begin{table}%t8 \caption{\label{PrCN_parameters}Spectroscopic parameters$^a$ (MHz) of \textit{n}-propyl cyanide.} \small%\centerline $${ \begin{tabular}{lr@{}lr@{}l} \hline \hline Parameter & \multicolumn{2}{c}{\textit{anti}} & \multicolumn{2}{c}{\textit{gauche}} \\ \hline $A$ & 23~668&.319~31~(143) & 10~060&.416~49~(108) \\ $B$ & 2268&.146~892~(147) & 3267&.662~408~(301) \\ $C$ & 2152&.963~946~(168) & 2705&.459~572~(290) \\ $D_K \times 10^3$ & 240&.653~(29) & 60&.235~(6) \\ $D_{JK} \times 10^3$ & $-$10&.826~31~(92) & $-$18&.264~70~(117) \\ $D_J \times 10^6$ & 398&.674~(69) & 3195&.064~(207) \\ $d_1 \times 10^6$ & $-$46&.637~(42) &$-$1037&.470~(55) \\ $d_2 \times 10^6$ & $-$0&.590~1~(59) & $-$77&.186~4~(183) \\ $H_K \times 10^6$ & 2&.5 & 1&.806~(18) \\ $H_{KJ} \times 10^9$ & 372&.4~(24) & $-$517&.3~(35) \\ $H_{JK} \times 10^9$ & $-$20&.67~(20) & 9&.92~(68) \\ $H_J \times 10^9$ & 0&.353~(11) & 4&.486~(56) \\ $h_1 \times 10^9$ & 0&.117~(14) & 2&.505~(29) \\ $h_2 \times 10^{12}$ & &$-$ & 524&.6~(135) \\ $h_3 \times 10^{12}$ & &$-$ & 111&.3~(31) \\ $L_{KKJ} \times 10^{12}$ & &$-$ & 30&.6~(31) \\ $L_{JK} \times 10^{12}$ & &$-$ & $-$4&.11~(78) \\ \hline \end{tabular}}$$ \medskip $^a$ Watson's $S$-reduction was used in the representation~$I^r$. Numbers in parentheses are one standard deviation in units of the least significant figures. Parameter values with no uncertainties given were estimated. A~long dash indicates parameters that are determinable in theory, but could not be determined with significance here. \end{table}