\begin{table}%ta.1 %\centering \par \caption{\label{tab:transitions3}Molecular constants~$^{\alpha}$.} %\centerline {\small\begin{tabular}{lccccc} \hline \hline\noalign{\smallskip} Species & Transition & Frequency & $E_{\rm u}$/k & $A_{\rm ul}$ & $n_{\rm crit}~^{\beta}$ \\ & ($J_{K}$) & (GHz) & ($K$) & (s$^{-1}$) & (\cmmthree) \\ \hline \hcop \rule{0pt}{4mm}& $1\rarr0$ &89.188526 &4.280 &$3.020\times 10^{-5}$ & $3.0 \times 10^{5}$~$^{\dagger}$\\ \hthirteencop \rule{0pt}{4mm} & $1\rarr0$ & ~~86.754330 & ~~4.160 & ~~2.800$\times 10^{-5}$ & $3.0 \times 10^{5}$~$^{\dagger}$\\ \thirteenco \rule{0pt}{4mm} & $1\rarr 0$ & 110.210353 & ~~5.288 & $6.389 \times 10^{-8}$ & $6.5 \times 10^2$~$^{\dagger}$ \\ \ceighteeno & $1\rarr 0$ & 109.782173 & 5.267 & 4.961$\times 10^{-7}$ & -- \\ CS & $2\rarr 1$ & ~~97.980950 & ~~7.052 & $1.703 \times 10^{-5}$ & $2.0\times~10^5$ \\ \ntwohp \rule{0pt}{4mm} & $1_{1}\rarr 0_{1}$ & ~~93.171880 & ~~4.471 & $3.654 \times 10^{-5}$ & $2 \times 10^{5}$~$^{un}$\\ & $1_{2}\rarr 0_{1}$ & ~~93.173700 & -- & -- & -- \\ & $1_{0}\rarr 0_{1}$ & ~~93.176130 & -- & -- & -- \\ \nhthree \rule{0pt}{4mm} & $1_{1}\rarr 1^{\prime}_{1^{\prime}}$ & ~~23.694480 & 17.215 & $1.67\times 10^{-7}$ & $2\times 10^{4}$~$^{sw}$\\ & $2_{2}\rarr 2^{\prime}_{~2^{\prime}}$ & ~~23.722630 & 63.866 & 2.29$\times 10^{-7}$ &\\ \hline \end{tabular}} \medskip $^{\alpha}$~Unless otherwise noted, all values quoted here are sourced from the NASA Jet Propulsion Lab (JPL) spectral line database \citep{Pickett1998}; $^{\beta}$~Critical density values marked with a $\dagger$ are calculated from the formula ${n_{\rm crit} = A_{\rm ul}/\gamma_{_{H_2}}}$, where ${\rm \gamma_{_{\rm H_2}}}$ is the ``standard'' collisional rate coefficient for H$_2$, assumed equal to 10$^{10}$~${\rm cm^3.s^{-1}.H_2}$-${\rm molecules^{-1}}$. Other values are referenced as follows: $^{un}$~\citet{Ungerechts1997}, $^{sw}$~\cite{Swade1989}. \end{table}