\begin{table}%t1 \caption{Chemical surface reactions.} %\centerline { \begin{tabular}{cll} \hline \hline {Solid $s$} & {Surface reaction $r$} & {Key species} \\ \hline TiO$_2$[s] & TiO$_2$ $\longrightarrow$ TiO$_2$[s] & TiO$_2$ \\ rutile & Ti + 2 H$_2$O $\longrightarrow$ TiO$_2$[s] + 2 H$_2$ & Ti \\ (1) & TiO + H$_2$O $\longrightarrow$ TiO$_2$[s] + H$_2$ & TiO \\ (A) & TiS + 2 H$_2$O $\longrightarrow$ TiO$_2$[s] + H$_2$S + H$_2$ & TiS \\ \hline SiO$_2$[s] & SiO$_2$ $\longrightarrow$ SiO$_2$[s] & SiO$_2$ \\ silica & SiO + H$_2$O $\longrightarrow$ SiO$_2$[s] + H$_2$ & SiO \\ (3)(B) & SiS + 2 H$_2$O $\longrightarrow$ SiO$_2$[s] + H$_2$S + H$_2$ & SiS \\ \hline Fe[s] & Fe $\longrightarrow$ Fe[s] & Fe \\ solid iron & FeO + H$_2$ $\longrightarrow$ Fe[s] + H$_2$O & FeO \\ (1) & FeS + H$_2$ $\longrightarrow$ Fe[s] + H$_2$S & FeS \\ (B) & Fe(OH)$_2$ + H$_2$ $\longrightarrow$ Fe[s] + 2 H$_2$O & Fe(OH)$_2$ \\ \hline MgO[s] & MgO $\longrightarrow$ MgO[s] & MgO \\ periclase & Mg + H$_2$O $\longrightarrow$ MgO[s] + H$_2$ & Mg \\ (3) & 2 MgOH $\longrightarrow$ 2 MgO[s] + H$_2$ & $1/2$MgOH\\ (B) & Mg(OH)$_2$ $\longrightarrow$ MgO[s] + H$_2$O & Mg(OH)$_2$\\ \hline MgSiO$_3$[s]& Mg + SiO + 2 H$_2$O $\longrightarrow$ MgSiO$_3$[s] + H$_2$ & $\min\{$Mg, SiO$\}$\\ enstatite & Mg + SiS + 3 H$_2$O $\longrightarrow$ MgSiO$_3$[s] + H$_2$S + 2 H$_2$ & $\min\{$Mg, SiS$\}$\\ (3) & 2 MgOH + 2 SiO + 2 H$_2$O $\longrightarrow$ 2 MgSiO$_3$[s] + 3 H$_2$ & $\min\{1/2$MgOH, 1/2SiO$\}$ \\ (C) & 2 MgOH + 2 SiS + 2 H$_2$O $\longrightarrow$ 2 MgSiO$_3$[s] + 2 H$_2$S + 2 H$_2$ & $\min\{1/2$MgOH, 1/2SiS$\}$ \\ & Mg(OH)$_2$ + SiO $\longrightarrow$ 2 MgSiO$_3$[s] + H$_2$ & $\min\{$Mg(OH)$_2$, SiO$\}$ \\ & Mg(OH)$_2$ + SiS + H$_2$O $\longrightarrow$ MgSiO$_3$[s] + H$_2$S+ H$_2$ & $\min\{$Mg(OH)$_2$, SiS$\}$ \\ \hline Mg$_2$SiO$_4$[s] & 2 Mg + SiO + 3 H$_2$O $\longrightarrow$ Mg$_2$SiO$_4$[s] + 3 H$_2$ & $\min\{1/2$Mg, SiO$\}$\\ forsterite & 2 MgOH + SiO + H$_2$O $\longrightarrow$ Mg$_2$SiO$_4$[s] + 2 H$_2$ & $\min\{1/2$MgOH, SiO$\}$\\ (3) & 2 Mg(OH)$_2$ + SiO $\longrightarrow$ Mg$_2$SiO$_4$[s] + H$_2$O + H$_2$ & $\min\{1/2$Mg(OH)$_2$, SiO$\}$ \\ (C) & 2 Mg + SiS + 4 H$_2$O $\longrightarrow$ Mg$_2$SiO$_4$[s] + H$_2$S + 3 H$_2$ & $\min\{1/2$Mg, SiS\} \\ & 2 MgOH + SiS + 2 H$_2$O $\longrightarrow$ Mg$_2$SiO$_4$[s] + H$_2$S + 2 H$_2$ & $\min\{1/2$MgOH, SiS\}\\ & 2 Mg(OH)$_2$ + SiS $\longrightarrow$ Mg$_2$SiO$_4$[s] + H$_2$ + H$_2$S & $\min\{1/2$Mg(OH)$_2$, SiS\} \\ \hline Al$_2$O$_3$[s] & 2 AlOH + H$_2$O $\longrightarrow$ Al$_2$O$_3$[s] + 2 H$_2$ & 1/2AlOH \\ aluminia & 2 AlH + 3 H$_2$O $\longrightarrow$ Al$_2$O$_3$[s] + 4 H$_2$& 1/2AlH\\ (3) & Al$_2$O + 2 H$_2$O $\longrightarrow$ Al$_2$O$_3$[s] + 2 H$_2$ & Al$_2$O\\ (D) & 2 AlS + 3 H$_2$O $\longrightarrow$ Al$_2$O$_3$[s] + 2 H$_2$S + H$_2$ & 1/2AlS\\ & 2 AlO$_2$H $\longrightarrow$ Al$_2$O$_3$[s] + H$_2$O & 1/2AlO$_2$H\\ \hline \end{tabular}} \medskip \par $r$ assumed to form the solid materials s. The efficiency of the reaction is limited by the collision rate of the key species. The notation 1/2 in the r.h.s.~column means that only every second collision (and sticking) event initiates one reaction. Data sources for the supersaturation ratios (and saturation vapour pressures): (1) \citet{HW06}; (2) \citet{Nu06}; (3) \citet{Sh90}. Data sources for the pure solid refractive indices: (A) \citet{Po99}; (B) \citet{Pa85,Pa91}; (C) \citet{Ja03}; (D) \citet{Pa91}, \citet{Be97}. \label{tab:chemreak2} \end{table}