\begin{table}%t3 %\begin{center} \par \caption{Spectroscopic parameters$^a$ (MHz) of monodeuterated methyl cyanide, CH$_2$DCN and dimensionless weighted standard deviation wrms.} \label{parameter_1D} % \smallskip $$ \begin{tabular}[t]{lr@{}l} \hline \hline Parameter & \multicolumn{2}{c}{Value} \\ \hline $A$ & 121~074&.677~(20) \\ $B$ & 8~759&.197~94~(23) \\ $C$ & 8~608&.542~55~(24) \\ $D_K$ & 1&.97 \\ $D_{JK} \times 10^3$ & 143&.336~1~(138) \\ $D_J \times 10^3$ & 3&.469~982~(137) \\ $d_1 \times 10^6$ & $-$79&.164~(46) \\ $d_2 \times 10^6$ & $-$4&.776~(35) \\ $H_K \times 10^6$ & 100&. \\ $H_{KJ} \times 10^6$ & 1&.688~(192) \\ $H_{JK} \times 10^9$ & 837&.5~(49) \\ $H_J \times 10^{12}$ & 400&.4~(191) \\ $h_1 \times 10^{12}$ & 149&.0~(84) \\ $L_{KKJ} \times 10^9$ & $-$10&.82~(68) \\ $L_{JK} \times 10^{12}$ & 58&.~(28) \\ $L_{JJK} \times 10^{12}$ & $-$5&.37~(55) \\ wrms & 0&.740 \\ \hline \end{tabular} $$ %\end{center} \par $^a$ Watson's $S$ reduction has been used in the representation $I^r$. Numbers in parentheses are one standard deviation in units of the least significant figures. Parameters without quoted uncertainties have been estimated; see Sect.~\ref{a_and_d}.%\\ \end{table}