\begin{table}%t4 %%\centering \par \caption{\label{tab:newspec}Assignment of infrared absorption features produced by the radiolysis of the H$_2$O:NH$_3$:CO ice (1:0.6:0.4) by 46~MeV~Ni ions at 13~K and after warming to 300~K.} %\centerline { \small \begin{tabular}{ l l l l r } \hline \hline Frequency & Wavelength & Temp. & Molecule & Notes \\ (cm$^{-1}$)& ($\mu$m) & (K) & & \\ \hline 2233 & 4.48 & 13 & N$_2$O & [1,2] \\ 2218--2200 & 4.51-4.54 & 300 & nitriles$^\dag$ & [8] \\ 2168 & 4.61 & 13, 300 & OCN$^-$ & [1,3,4,7] \\ 2147 & 4.66 & 300 & aliph. isocyanide$^\dag$ & [8] \\ $\sim$2112 & 4.73 & 300 & NCO$_2^\dag$ & [2] \\ 1725 & 5.80 & 300 & ester$^\dag$ & [5] \\ 1683 & 5.94 & 300 & amides$^\dag$ & [5] \\ 1652 & 6.05 & 300 & asym-N$_2$O$_3^\dag$ & [2] \\ 1637 & 6.11 & 13 & ? & \\ 1593 & 6.28 & 300 & NH$_3^+$CH$_2$COO$^{-\dag}$ & [6] \\ 1558 & 6.42 & 300 & ? & \\ 1533 & 6.52 & 300 & ? & \\ 1506 & 6.64 & 300 & NH$_3^+$CH$_2$COO$^{-\dag}$ & [6] \\ $\sim$1490 & 6.71 & 13 & NH$_4^+$ & [1,3,7] \\ 1474 & 6.78 & 13 & NO$_3^\dag$ & [2] \\ 1440 & 6.94 & 13 & NH$_3^+$CH$_2$COO$^{-\dag}$ & [6] \\ 1415 & 7.07 & 300 & NH$_3^+$CH$_2$COO$^{-\dag}$ & [6] \\ $\sim$1370 & 7.30 & 13, 300 & HMT$^\dag$ & [5] \\ & & & HCOO$^{-}$ & [5,9] \\ $\sim$1338 & 7.47 & 13, 300 & NH$_3^+$CH$_2$COO$^{-\dag}$ & [6] \\ & & & NH$_2$CH$_2$COO$^{-\dag}$ & [6] \\ & & & HCOO$^-$ & [9] \\ 1305 & 7.66 & 13 & N$_2$O$_3^\dag$; N$_2$O$_4^\dag$ & [2] \\ 1283 & 7.80 & 300 & N$_2$O$^\dag$ & [2] \\ \hline \end{tabular}} \medskip $^\dag$Tentative assignment. [1] Proton bombardment of several ices (Hudson et~al. \cite{Hudson2001}); [2] Electron bombardment of N$_2$:CO$_2$ (Jamieson et~al. \cite{Jamieson2005}); [3] Hudson \& Moore (\cite{Hudson2000}; [4] van~Broekhuizen et~al. \cite{van2005}; [5] UV~photolysis of H$_2$O:NH$_3$:CH$_3$OH:CO:CO$_2$ ice (Munoz Caro \& Shutte \cite{Munoz2003}); [6] electron bombardment of CH$_3$NH$_2$:CO$_2$ ice (Holtom et~al. \cite{Holtom2005}); [7]~UV photolysis of ammonia-containing ices (Demyk et~al. \cite{Demyk1998}); [8]~UV photolysis of N$_2$:CH$_4$ ices at various pressures (Imanaka et~al. \cite{Imanaka2004}); [9]~proton bombardment of H$_2$O:NH$_3$:CO ice (Hudson \& Moore \cite{Hudson2001}). \end{table}