\begin{table}%t2 %\centering \par \caption{\label{models_used}Summary of the dark cloud (DC), hot core (HC) and PDR models used to model the time dependent HNCO gas-phase abundance.} \begin{tabular}{cccll} \hline\hline \noalign{\smallskip} Model & $T$~(K) & $n_{{\rm H}}$~(cm$^{-3}$) & Initial chemistry & HNCO formation chemistry \\ \hline DC1 & 10 & $2.0 \times10^{4}$ & Atomic & Reaction~c only\\ DC2 & 10 & $2.0 \times10^{4}$ & Atomic & Reactions c,d,e and f\\ DC3 & 10 & $2.0 \times10^{4}$ & Atomic & Reactions d,e,f and g\\ DC4 & 10 & $2.0 \times10^{4}$ & Atomic & Reactions c,d,e,f and g \\ HC1 & 200 & $2.0 \times10^{7}$ & CC1 & All\\ HC2 & 200 & $2.0 \times10^{7}$ & CC2 & Gas phase only\\ HC3 & 200 & $2.0 \times10^{7}$ & CC3 & Surface only (reactions a,b)\\ HC4 & 200 & $2.0 \times10^{7}$ & CC4 & All\\ HC5 & 20 & $2.0 \times10^{7}$ & CC5 & All\\ HC6 & 20 & $2.0 \times10^{7}$ & CC1 & All\\ HC7 & 50 & $2.0\times10^{7}$ & CC6 & All\\ HC8 & 50 & $2.0 \times10^{7}$ & CC1 & All\\ HC9 & 100 & $2.0 \times10^{7}$ & CC7 & All\\ HC10 & 100 & $2.0\times10^{7}$ & CC1 & All\\ PDR1 & 50 & $2.0\times10^{4}$ & Atomic & All\\ PDR2 & 50 & $2.0\times10^{4}$ & Atomic & Gas phase only\\ PDR3 & 50 & $2.0\times10^{4}$ & Atomic & Surface only (reactions a,b)\\ PDR4 & 50 & $2.0\times10^{7}$ & CC1 & All\\ PDR5 & 50 & $2.4\times10^{5}$ & CC1 & All\\ \hline \end{tabular} \tablefoot{$T$ is the gas-phase temperature and $n_{{\rm H}}$ is the total hydrogen number density (both held constant). The initial chemistry was either~$atomic$, where all species (except H) were in their elemental form, or $evolved$, where abundances from a collapsed cloud (CC) model were used. The collapsing cloud models are listed in a separate table. } \end{table}