\begin{table}%t1 \caption{\label{table:1}Observed line parameters in TMC-1 and L1527.} \par %\centering \par \small\begin{tabular}{llr rcc ccc} \hline \hline \noalign{\smallskip} &&&\multicolumn{1}{c}{Frequency}&$T_{\rm MB}$\tablefootmark{b} & ${\it \Delta} v$\tablefootmark{b} & $\int T_{\rm MB} {\rm d}v$ ($3 {\sigma}$) & rms\tablefootmark{c} & $V_{\rm LSR}$\tablefootmark{b} \\ \multicolumn{1}{c}{Species}&\multicolumn{1}{c}{Transition}&\multicolumn{1}{c}{$S$\tablefootmark{a}}&\multicolumn{1}{c}{(GHz)}&(K)&(km s$^{-1}$)&(K km s$^{-1}$)&(mK)&(km s$^{-1}$) \\ \hline \multicolumn{9}{c}{TMC-1} \\ CCH&$J=3/2{-}1/2 \ F=1{-}1$&0.17&87.284156(30)&1.538(55)&0.49(2)&0.795(13)&8.8 &5.907(9) \\ $N=1{-}0$&$J=3/2{-}1/2 \ F=2{-}1$&1.67&87.316925(4)&2.144(78)&0.59(3)&1.336(15)&8.7 &5.869(11) \\ &$J=3/2{-}1/2 \ F=1{-}0$&0.83&87.328624(6)&1.571(59)&0.56(2)&0.924(15)&9.2 &5.912(10) \\ &$J=1/2{-}1/2 \ F=1{-}1$&0.83&87.402004(5)&1.711(101)&0.55(4)&0.963(22)&13.4 &5.853(16) \\ &$J=1/2{-}1/2 \ F=0{-}1$&0.33&87.407165(11)&1.549(110)&0.53(4)&0.860(21)&14.6 &5.789(19) \\ &$J=1/2{-}1/2 \ F=1{-}0$&0.17&87.446512(23)&1.424(52)&0.52(2)&0.808(15)&9.5 &5.914(9) \\ \cline{2-9} C$^{13}$CH&$J=3/2{-}1/2 \ F_1=2{-}1 \ F=5/2{-}3/2$&2.00 &85.2293354(26)&0.059(5)&0.52(5)&0.032(5)&3.1 &5.84(2)\tablefootmark{d} \\ $N=1{-}0$&$J=3/2{-}1/2 \ F_1=2{-}1 \ F=3/2{-}1/2$&1.26 &85.2328050(22)&0.035(6)&0.56(10)&0.020(5)&3.2 &5.89(4)\tablefootmark{d} \\ &$J=3/2{-}1/2 \ F_1=1{-}0 \ F=3/2{-}1/2$&1.27 &85.2569879(33)&0.041(5)&0.43(6)&0.019(4)&3.4 &5.83(3)\tablefootmark{d} \\ &$J=1/2{-}1/2 \ F_1=1{-}1 \ F=1/2{-}3/2$&0.62 &85.3039898(33)&0.021(4)\tablefootmark{e}&0.69(17)\tablefootmark{e}&0.014(6)\tablefootmark{e}&2.7 &5.89(7)$^{{\rm d, e}}$ \\ &$J=1/2{-}1/2 \ F_1=1{-}1 \ F=3/2{-}3/2$&1.21 &85.3074593(33)&0.034(4)&0.53(8)&0.020(5)&2.9 &5.83(3)\tablefootmark{d} \\ \cline{2-9} $^{13}$CCH&$J=3/2{-}1/2 \ F_1=2{-}1 \ F=5/2{-}3/2$&2.00 &84.119329(17)&0.037(4)&0.52(7)&0.020(4)&2.8 &5.84(3) \\ $N=1{-}0$&$J=3/2{-}1/2 \ F_1=2{-}1 \ F=3/2{-}1/2$&1.22 &84.124143(20)&0.026(5)&0.46(10)&0.012(4)&2.8 &5.80(4) \\ &$J=1/2{-}1/2 \ F_1=0{-}1 \ F=1/2{-}1/2$&0.46 &84.183977(28)&0.026(5)\tablefootmark{e}&0.28(7)\tablefootmark{e}&0.007(3)\tablefootmark{e}&3.5 &5.71(3)\tablefootmark{e} \\ \hline \multicolumn{9}{c}{L1527} \\ CCH&$J=3/2{-}1/2 \ F=1{-}1$&0.17&87.284156(30)&1.932(19)&0.53(1)&1.112(20)&12.8 &6.026(2) \\ $N=1{-}0$&$J=3/2{-}1/2 \ F=2{-}1$&1.67&87.316925(4)&$--$&$--$&3.592(21)&13.3 &$--$ \\ &$J=3/2{-}1/2 \ F=1{-}0$&0.83&87.328624(6)&$--$&$--$&2.447(23)&14.4 &$--$ \\ &$J=1/2{-}1/2 \ F=1{-}1$&0.83&87.402004(5)&$--$&$--$&2.602(21)&13.3 &$--$ \\ &$J=1/2{-}1/2 \ F=0{-}1$&0.33&87.407165(11)&2.775(25)&0.60(1)&1.801(24)&13.5 &5.846(3) \\ &$J=1/2{-}1/2 \ F=1{-}0$&0.17&87.446512(23)&2.014(19)&0.52(1)&1.162(21)&13.3 &6.011(2) \\ \cline{2-9} C$^{13}$CH&$J=3/2{-}1/2 \ F_1=2{-}1 \ F=5/2{-}3/2$&2.00 &85.2293354(26)&0.163(10)&0.43(3)&0.078(6)&4.4 &5.950(5)\tablefootmark{f} \\ $N=1{-}0$&$J=3/2{-}1/2 \ F_1=2{-}1 \ F=3/2{-}1/2$&1.26 &85.2328050(22)&0.104(10)&0.56(3)&0.060(7)&3.9 &5.950(5)\tablefootmark{f} \\ &$J=3/2{-}1/2 \ F_1=1{-}0 \ F=1/2{-}1/2$&0.65 &85.2477276(33)&0.058(7)&0.50(7)&0.028(6)&3.9 &5.950(5)\tablefootmark{f} \\ &$J=3/2{-}1/2 \ F_1=1{-}0 \ F=3/2{-}1/2$&1.27 &85.2569879(33)&0.098(8)&0.45(4)&0.047(6)&4.2 &5.950(5)\tablefootmark{f} \\ &$J=1/2{-}1/2 \ F_1=1{-}1 \ F=1/2{-}3/2$&0.62 &85.3039898(33)&0.046(5)&0.55(7)&0.026(4)&2.4 &5.950(5)\tablefootmark{f} \\ &$J=1/2{-}1/2 \ F_1=1{-}1 \ F=3/2{-}3/2$&1.21 &85.3074593(33)&0.110(7)&0.42(3)&0.050(3)&2.7 &5.950(5)\tablefootmark{f} \\ &$J=1/2{-}1/2 \ F_1=0{-}1 \ F=1/2{-}1/2$&0.62 &85.3140918(33)&0.051(5)&0.42(4)&0.024(4)&2.8 &5.950(5)\tablefootmark{f} \\ \cline{2-9} $^{13}$CCH&$J=3/2{-}1/2 \ F_1=2{-}1 \ F=5/2{-}3/2$&2.00 &84.119329(17)&0.093(5)&0.48(3)&0.047(2)&1.6 &5.94(1) \\ $N=1{-}0$&$J=3/2{-}1/2 \ F_1=2{-}1 \ F=3/2{-}1/2$&1.22 &84.124143(20)&0.056(6)&0.53(7)&0.033(3)&1.6 &5.95(3) \\ &$J=3/2{-}1/2 \ F_1=1{-}0 \ F=1/2{-}1/2$&0.66 &84.151352(16)&0.030(5)&0.48(9)&0.015(2)&1.5 &5.90(4) \\ &$J=3/2{-}1/2 \ F_1=1{-}0 \ F=3/2{-}1/2$&1.33 &84.153305(15)&0.059(4)&0.51(4)&0.034(2)&1.4 &5.89(2) \\ &$J=1/2{-}1/2 \ F_1=0{-}1 \ F=1/2{-}1/2$&0.46 &84.183977(28)&0.024(3)&0.36(5)&0.011(2)&2.0 &5.90(2) \\ &$J=1/2{-}1/2 \ F_1=1{-}1 \ F=1/2{-}3/2$&0.46 &84.192487(30)&0.029(4)&0.50(8)&0.016(4)&2.8 &5.90(3) \\ &$J=1/2{-}1/2 \ F_1=1{-}1 \ F=3/2{-}3/2$&1.22 &84.206865(19)&0.067(3)&0.46(3)&0.033(2)&1.7 &5.90(1) \\ &$J=1/2{-}1/2 \ F_1=1{-}1 \ F=1/2{-}1/2$&0.22 &84.225376(20)&$--$&$--$&$\leq$ 4.6&3.1 &$--$ \\ \hline \end{tabular} \tablefoot{ The numbers in parentheses represent the errors in units of the last significant digits. \tablefoottext{a}{Intrinsic line strength.} \tablefoottext{b}{Obtained by the Gaussian fit.} \tablefoottext{c}{The rms noise at an emission free region averaged over the line width. For non detected lines, the line widths of 0.5~km~s$^{-1}$ are assumed.} \tablefoottext{d}{Calculated on the basis of the rest frequencies of the C$^{13}$CH lines obtained in this study (Table~\ref{table:A1}).} \tablefoottext{e}{Marginal detection.} \tablefoottext{f}{See Sect.~3.1 and Appendix~A.}}\vspace*{1mm} \end{table}