\begin{table}%t2 \caption{\label{intensites}Relative NIR clathrate hydrate and methane ice integrated intensities\tablefootmark{a}.} %\centerline { \small\begin{tabular}{l c c} \hline\hline\noalign{\smallskip} Dominant transitions &Clathrate (5.6~K) &Methane ice\tablefootmark{b} \\ \hline $3\nu_4$ &0.063 &$\sim$0.054\tablefootmark{c} \\ $\nu_2+2\nu_4$ &0.010 &0.013 \\ $\nu_1+\nu_4$ &0.511 &0.524 \\ $\nu_3+\nu_4$ &{\it 1.0}\tablefootmark{a} &{\it1.0}\tablefootmark{a} \\ $\nu_2+\nu_3$ &0.099 &0.095 \\ $\nu_3+2\nu_4$ &0.014 &0.014 \\ $2\nu_2+2\nu_4$ &0.004 &$\sim$0.004\tablefootmark{d} \\ $\nu_2+\nu_3+\nu_4$ &0.028 &0.029 \\ $2\nu_3$ &0.042 &0.061 \\ \hline \end{tabular}} \tablefoot{ \tablefoottext{a}{Normalised to the $\nu_3+\nu_4$ transitions;} \tablefoottext{b}{Brunetto et~al. (\cite{Brunetto2008}) at 16~K;} \tablefoottext{c}{intensity before normalisation estimated from the ratio of absorption coefficient of $(\nu_1+\nu_4)$/$3\nu_4$ from Quirico \& Schmitt (\cite{Quirico1997}) at 21~K, assuming the same line width for both transitions;} \tablefoottext{d}{ integrated intensity before normalisation estimated from the spectrum of the blended $(2\nu_2+2\nu_4)$/$(\nu_3+2\nu_4)$ lines from Fig.~\ref{Fig_deformed}b in Quirico \& Schmitt (\cite{Quirico1997}) at 21~K.}} \end{table}