\begin{table}%t3 \caption{\label{exp_conditions}Calculated cages occupancy equilibrium.} %\centerline { \small\begin{tabular}{c c c c c} \hline\hline\noalign{\smallskip} CH$_4$ & Temperature$^a$ & Pressure\tablefootmark{a} & Obs. \tablefootmark{b} &Pred.\tablefootmark{b}\\ (mol. ratio \%) &(K) & (Bar) & L/S &L/S\\ \hline 5 & 250 & 40 &$0.46\pm 0.2$ &0.45\\ 15 & 255 & 50 &$0.9\pm 0.16$ &0.86\\ 50 & 240 & 60 &$1.61\pm 0.29$ &1.78\\ 100 & 255 & 40 &3.00 &3.00\\ \hline \end{tabular}} \tablefoot{ \tablefoottext{a}{Formation conditions;} \tablefoottext{b}{assuming and normalised to ${\rm L/S} = 3$ for the 100\% methane clathrate hydrate}} \end{table}