\begin{table}%t4 \caption{Comparison with UMIST and Ohio State Chemical Network rate constants and their implied branching fractions\tablefootmark{a}.} \label{udfarates} %\centerline {\begin{tabular}{llll} \hline \hline Reaction products & $\alpha$ & $\beta$ & Branch. Fract. \\ & $\times$10$^{-7}$ & & (\%) \\ \hline OSU\\ CH$_{3}$OCH$_{4}^{+}$~+~e$^-$ $\rightarrow$ \\% & 4.50~$\times$~10$^{-7}$ & $-$0.50 & 100 \\ ~~~~~~CH$_{3}$OCH$_{3}$+H & 1.50 & $-$0.50 & 33.3 \\ CH$_{3}$OH+CH$_{3}$ & 1.50 & $-$0.50 & 33.3 \\ CH$_{3}$+ CH$_{4}$+O & 1.50 & $-$0.50 & 33.3 \\ Total & 4.50 & $-$0.50 & 100 \\ \\ UMIST\\ CH$_{3}$OCH$_{4}^{+}$+e$^-$ $\rightarrow$ \\% & 3.00~$\times$~10$^{-7}$ & $-$0.50 & 100 \\ ~~~~~~CH$_{3}$OCH$_{3}$+H & 1.50 & $-$0.50 & 50 \\ CH$_{3}$OH+CH$_{3}$ & 1.50 & $-$0.50 & 50 \\ Total & 3.00 & $-$0.50 & 100 \\ \\ Current data\\ \chem{(CD_3)_2OD^+~+~e^- \rightarrow} \\% & 17~$\times$~10$^{-7}$ & $-$0.70 & 100 \\ ~~~~~~CH$_{3}$OCH$_{3}$+H & 0.85 & $-$0.70 & 7 \\ CH$_{3}$OH+CH$_{3}$ & $\leq$9.18 & $-$0.70 & $\leq$49 \\ CH$_{3}$+ CH$_{4}$+O & $\leq$6.97 & $-$0.70 & $\leq$44 \\ Total & 17 & $-$0.70 & 100 \\ \\ OSU\\ H$_{5}$C$_{2}$O$^{+}$~+~e$^-$ $\rightarrow$ \\% & 7.50~$\times$~10$^{-7}$ & $-$0.50 & 100 \\ ~~~~~~CO+CH$_{4}$+H & 3.00 & $-$0.50 & 40 \\ H$_{2}$CO+CH$_{3}$ & 1.50 & $-$0.50 & 20 \\ CH$_{3}$CHO+H & 1.50 & $-$0.50 & 20 \\ H$_{2}$CCO+H$_2$+H & 1.50 & $-$0.50 & 20 \\ Total & 7.50 & $-$0.50 & 100 \\ \\ UMIST\\ \chem{CH_3CHOH^+~+~e^-\rightarrow} \\% & 6.00~$\times$~10$^{-7}$ & -0.50 & 100 \\ ~~~~~~CO+CH$_{4}$+H & 3.00 & $-$0.50 & 50 \\ H$_{2}$CO+CH$_{3} $ & 1.50 & $-$0.50 & 25 \\ CH$_{3}$CHO+H & 1.50 & $-$0.50 & 25 \\ Total & 6.00 & $-$0.50 & 100 \\ \\ Current data\\ \chem{CD_3OCD_2^+ + e^- \rightarrow} \\% & 17~$\times$~10$^{-7}$ & -0.77 & 100 \\ ~~~~~~CO+CH$_{4}$+H & $\leq$17 & $-$0.77 & $\leq$100 \\ H$_{2}$CO+CH$_{3}$ & $\leq$17 & $-$0.77 & $\leq$100 \\ CH$_{3}$CHO+H & 0 & $-$0.77 & 0\\ H$_{2}$CCO+H$_2$+H & 0 & $-$0.77 & 0 \\ Total & 17 & $-$0.77 & 100 \\ \hline \end{tabular}} \tablefoot{\tablefoottext{a}{Rate constants are $k(T) = \alpha$*($T$/300)$^\beta$~cm$^3$~s$^{-1}$ and are compared to the product channel upper limits of the current data. Note that the exact isomers for \chem{CH_3OCH_2^+} were not found in the model databases.}} \vspace*{1mm} \end{table}