\begin{table}%t2 %\centering \par \caption{\label{der-parameter}Derived spectroscopic parameters$^a$ (cm$^{-1}$, MHz, unitless) of methylidynium, $^{12}$CH$^+$ in its $X\ ^1\Sigma ^+$ and $A\ ^1\Pi$ electronic states from a global fit involving four isotopologs.} \begin{tabular}[t]{lc} \hline \hline Parameter & \multicolumn{1}{c}{Value} \\ \hline\noalign{\smallskip} \multicolumn{2}{c}{$X\ ^1\Sigma ^+$} \\ \hline $Y_{10}$ & 2~857.569~2~(92) \\ ${\it \Delta} ^{\rm C} _{10}$ & $-$1.120~(137) \\ ${\it \Delta} ^{\rm H} _{10}$ & $-$1.715~9~(86) \\ $Y_{20}$ & $-$59.318~7~(60) \\ ${\it \Delta} ^{\rm H} _{20}$ & $-$1.578~(188) \\ $Y_{01}$ & 425~058.66~(248) \\ ${\it \Delta} ^{\rm C} _{01}$ & $-$7.974~9~(105) \\ ${\it \Delta} ^{\rm H} _{01}$ & $-$9.226~3~(76) \\ $Y_{11}$ & $-$14~859.0~(67) \\ ${\it \Delta} ^{\rm H} _{11}$ & $-$7.222~(33) \\ $Y_{02}$ & $-$41.905~(20) \\ ${\it \Delta} ^{\rm H} _{02}$ & $-$24.36~(86) \\ \hline\noalign{\smallskip} \multicolumn{2}{c}{$A\ ^1\Pi$} \\ \hline $T$(H)\tablefootmark{b} & 23~619.707~(5) \\ $T$(D)\tablefootmark{b} & 23~760.102~(5) \\ $Y_{10}$(H) & 1~864.485~(8) \\ ${\it \Delta} ^{\rm C} _{10}$(H) & 1.244~(145) \\ $Y_{10}$(D) & 1~367.294~(8) \\ ${\it \Delta} ^{\rm C} _{10}$(D) & $-$2.876~(306) \\ $Y_{01}$ & 356~391.8~(29) \\ ${\it \Delta} ^{\rm C} _{01}$ & $-$0.56~(33) \\ ${\it \Delta} ^{\rm H} _{01}$ & $-$1.630~(12) \\ $Y_{11}$ & $-$27~538.7~(71) \\ ${\it \Delta} ^{\rm H} _{11}$ & $-$1.604~(98) \\ \hline \end{tabular} \tablefoot{\tablefoottext{a}{The electronic term values $T$, and the vibrational parameters $Y_{i0}$ are given in cm$^{-1}$; all other $Y_{ij}$ are given in MHz; the ${\it \Delta} ^{\rm X} _{ij}$ are unitless. Numbers in parentheses are one standard deviation in units of the least significant figures.} \tablefoottext{b}{Determined with respect to the lowest allowed energy levels of each electronic state.}} \end{table}