\begin{table}%t3 \caption{\label{tab3}Predicted rotational transition frequencies between the low-lying rotational levels of CH$_2$D$^+$ in the ground state (in MHz).} \small%\centering \par \begin{tabular}{cr@{}lcr@{}l} \hline\hline\noalign{\smallskip} \multicolumn{3}{c}{$para$-CH$_2$D$^+$}&\multicolumn{3}{c}{$ortho$-CH$_2$D$^+$} \\ \multicolumn{1}{c}{Transition}& \multicolumn{2}{c}{Frequency\tablefootmark{a}} &\multicolumn{1}{c}{ Transition}&\multicolumn{2}{c}{Frequency\tablefootmark{a}} \\ \hline $1_{01}{-}0_{00}$ & 278~691.&656(26) & $2_{11}{-}1_{10}$ & 624~492.&647(21) \\ $2_{02}{-}1_{01}$ & 534~280.&362(153) & $2_{12}{-}1_{11}$ & 490~012.&249(31) \\ $3_{03}{-}2_{02}$ & 757~259.&34(30) & $3_{12}{-}2_{11}$ & 918~639.&68(25) \\ $4_{04}{-}3_{03}$ & 963~382.&45(25) & $3_{13}{-}2_{12}$ & 722~354.&621(26) \\ $5_{05}{-}4_{04}$ & 1~169~125.&70(66) & $4_{13}{-}3_{12}$ & 1~185~028.&50(69) \\ & & & $4_{14}{-}3_{13}$ & 945~398.&62(19) \\ $3_{21}{-}2_{20}$ & 913~931.&77(46) & $5_{14}{-}4_{13}$ & 1~414~577.&97(116) \\ $3_{22}{-}2_{21}$ & 835~464.&379(51) & $5_{15}{-}4_{14}$ & 1~161~990.&60(70) \\ $4_{22}{-}3_{21}$ & 1~244~857.&02(71) & & & \\ $4_{23}{-}3_{22}$ & 1~095~330.&70(32) & $4_{31}{-}3_{30}$ & 1~176~104.&86(86) \\ $5_{23}{-}4_{22}$ & 1~556~427.&93(128) & $4_{32}{-}3_{31}$ & 1~147~307.&54(43) \\ $5_{24}{-}4_{23}$ & 1~341~292.&62(76) & & & \\ & & & & & \\ $2_{20}{-}2_{21}$ & 23~015.&873(169) & $1_{10}{-}1_{11}$ & 67~273.&548(45) \\ $3_{21}{-}3_{22}$ & 101~483.&26(62) & $2_{11}{-}2_{12}$ & 201~753.&947(70) \\ $4_{22}{-}4_{23}$ & 251~009.&58(129) & $3_{12}{-}3_{13}$ & 398~039.&01(23) \\ & & & $4_{13}{-}4_{14}$ & 637~668.&89(103) \\ $3_{22}{-}3_{03}$ & 666~882.&54(289) & $5_{14}{-}5_{15}$ & 890~256.&25(269) \\ $4_{23}{-}4_{04}$ & 798~830.&79(279) & & & \\ \hline \end{tabular} \tablefoot{\tablefoottext{a}{The values in parentheses indicate one standard deviation to the last quoted digits.} }\vspace{2mm} \end{table}