\begin{table}%t1 \caption{\label{t1}List of molecular species and transitions observed with HIFI (Band 1b).} %\centering \par \begin{tabular}{lrrrrcccc} \hline\hline\noalign{\smallskip} \multicolumn{1}{c}{Transition} & \multicolumn{1}{c}{$\nu_{\rm 0}$\tablefootmark{a}} & \multicolumn{1}{c}{$E_{\rm u}$\tablefootmark{a}} & \multicolumn{1}{c}{$T_{\rm peak}$} & \multicolumn{1}{c}{rms} & \multicolumn{1}{c}{$V_{\rm peak}$} & \multicolumn{1}{c}{$V_{\rm min}$} & \multicolumn{1}{c}{$V_{\rm max}$} & \multicolumn{1}{c}{$F_{\rm int}$} \\ \multicolumn{1}{c}{} & \multicolumn{1}{c}{(MHz)} & \multicolumn{1}{c}{(K)} & \multicolumn{1}{c}{(mK)} & \multicolumn{1}{c}{(mK)} & \multicolumn{1}{c}{(km s$^{-1}$)} & \multicolumn{1}{c}{(km s$^{-1}$)} & \multicolumn{1}{c}{(km s$^{-1}$)} & \multicolumn{1}{c}{(K~km~s$^{-1}$)} \\ \hline o-H$_2$O(1$_{\rm 10}$--1$_{\rm 01}$) & 556~936.002 & 27 & 910(17) & 17 & --0.37(1.00) & --25.4 & +7.6 & 11.68(0.10) \\ CH$_3$OH E ($11_{2,9}-10_{1,9}$) & 558~344.500 & 168 & 47(10) & 10 & +0.60(1.00) & --2.9 & +2.7 & 0.16(0.02) \\ o-H$_2$CO(8$_{\rm 18}$--7$_{\rm 17}$) & 561~899.318 & 118 & 92(4)\tablefootmark{b} & 8 & +0.38(0.14)\tablefootmark{b} & --4.5 & +3.6 & 0.49(0.03)\tablefootmark{b} \\ CH$_3$OH E ($3_{2,2}-2_{1,2}$) & 568~566.054 & 32 & 42(8) & 8 & +0.60(1.00) & --2.6 & +2.7 & 0.31(0.02) \\ o-NH$_3$(1$_0$--0$_0$) & 572~498.068 & 28 & 122(7) & 7 & +1.03(0.80) & --6.9 & +5.0 & 0.89(0.03) \\ CO(5-4) & 576~267.931 & 83 & 883(10) & 10 & +1.60(1.00) & --36.5 & +6.0 & 49.30(0.07) \\ p-H$_2$CO(8$_{\rm 08}$--7$_{\rm 07}$) & 576~708.315 & 125 & 41(7) & 7 & +1.80(1.00) & --5.4 & +2.7 & 0.22(0.02) \\ CH$_3$OH A$^{-}$ ($2_{2,1}-1_{1,0}$) & 579~084.700 & 45 & 53(8) & 8 & +0.60(1.00) & --6.0 & +3.7 & 0.29(0.03) \\ CH$_3$OH E ($12_{1,12}-11_{1,11}$) & 579~151.003 & 178 & 44(8) & 8 & --0.30(1.00) & --4.0 & +4.0 & 0.25(0.02) \\ CH$_3$OH A$^{+}$ ($12_{0,12}-11_{0,11}$) & 579~459.639 & 181 & 48(7) & 7 & +0.90(1.00) & --3.9 & +4.9 & 0.27(0.02) \\ CH$_3$OH A$^{+}$ ($2_{2,0}-1_{1,1}$) & 579~921.342 & 45 & 42(7) & 7 & --0.60(1.00) & --3.3 & +2.6 & 0.21(0.02) \\ CH$_3$OH E ($12_{2,10}-11_{2,9}$) & 580~902.721 & 195 & 11(4) & 4 & --3.00(3.00) & --3.9 & +2.5 & 0.09(0.02) \\ CH$_3$OH A$^{+}$ ($6_{1,6}-5_{0,5}$) & 584~449.896 & 63 & 88(9) & 9 & --0.30(1.00) & --6.0 & +2.9 & 0.58(0.03) \\ CS(12--11) & 587~616.240 & 183 & 23(2)\tablefootmark{b} & 5 & --0.61(0.57)\tablefootmark{b} & --7.3 & +6.5 & 0.19(0.03)\tablefootmark{b} \\ CH$_3$OH A$^{+}$ ($7_{3,5}-6_{2,4}$) & 590~277.688 & 115 & 42(9) & 9 & +0.60(1.00) & --1.0 & +3.0 & 0.16(0.02) \\ CH$_3$OH A$^{-}$ ($7_{3,4}-6_{2,5}$) & 590~440.291 & 115 & 40(9) & 9 & --0.60(1.00) & --2.6 & +0.8 & 0.10(0.02) \\ CH$_3$OH E ($9_{0,9}-8_{1,8}$) & 590~790.957 & 110 & 40(10) & 10 & +0.60(1.00) & --4.7 & +4.3 & 0.28(0.03) \\ o-H$_2$CO(8$_{\rm 17}$--7$_{\rm 16}$) & 600~374.604 & 126 & 29(7)\tablefootmark{b} & 9 & --0.14(0.57)\tablefootmark{b} & --3.0 & +1.8 & 0.19(0.04)\tablefootmark{b} \\ CH$_3$OH E ($4_{2,3}-3_{1,3}$) & 616~979.984 & 41 & 47(6) & 6 & +0.90(1.00) & --4.5 & +2.6 & 0.26(0.02) \\ HCN(7--6) & 620~304.095 & 119 & 94(7) & 7 & --0.60(1.00) & --7.6 & +3.2 & 0.68(0.03) \\ HCO$^+$(7--6) & 624~208.180 & 119 & 30(3)\tablefootmark{b} & 8 & +0.53(0.47)\tablefootmark{b} & --3.6 & +4.5 & 0.11(0.03)\tablefootmark{b} \\ CH$_3$OH A$^{-}$ ($3_{2,2}-2_{1,1}$) & 626~626.302 & 52 & 18(5) & 5 & --1.20(4.00) & --2.5 & +6.3 & 0.18(0.07) \\ CH$_3$OH E ($13_{1,13}-12_{1,12}$) & 627~170.503 & 209 & 33(7) & 7 & --0.30(1.00) & --3.2 & +2.5 & 0.15(0.02) \\ CH$_3$OH A$^{+}$ ($13_{0,13}-12_{0,12}$) & 627~558.440 & 211 & 41(9) & 9 & +0.60(1.00) & --3.6 & +2.5 & 0.19(0.02) \\ CH$_3$OH A$^{+}$ ($3_{1,2}-2_{1,2}$) & 629~140.493 & 52 & 52(9) & 9 & +0.60(1.00) & --3.5 & +3.7 & 0.24(0.03) \\ CH$_3$OH A$^{+}$ ($7_{1,7}-6_{0,6}$) & 629~921.337 & 79 & 70(13) & 13 & +1.50(1.00) & --3.9 & +3.7 & 0.37(0.04) \\ o-H$_2$CO(9$_{\rm 19}$--8$_{\rm 18}$) & 631~702.813 & 149 & 66(4)\tablefootmark{b} & 9 & +0.45(0.17)\tablefootmark{b} & --1.5 & +2.6 & 0.22(0.02)\tablefootmark{b} \\ \hline \end{tabular} \tablefoot{CO and H$_2$O emission is discussed in Lefloch et~al. (\cite{letter2}). Peak velocity and intensity (in $T_{\rm a}$ scale), integrated intensity ($F_{\rm int}$), as well as the terminal velocities of the line emission ($V_{\rm min}$ and $V_{\rm max}$) are reported. \tablefoottext{a}{Frequencies and spectroscopic parameters have been extracted from the Jet Propulsion Laboratory molecular database (Pickett et~al. \cite{pickett}) for all the transition except those of CH$_3$OH, which have been extracted from the Cologne Database for Molecular Spectroscopy (M\"uller et~al. \cite{muller}). Upper level energies refer to the ground state of each symmetry.} \tablefoottext{b}{Gaussian fit.}}\vspace*{2.7mm} \end{table}