\begin{table}%t1 \caption{\label{table-I}Molecular observations in comet C/2006~W3 (Christensen).} \vspace*{-1.5mm} %\centering \par \begin{tabular}{lcclclcc} \hline\hline\noalign{\smallskip} \phantom{IRAM00}2009 UT date & $\langle r_{\rm h}\rangle $ & $\langle \Delta \rangle $ & Line & Intensity & Unit &Velocity shift & Prod. rate\\ \phantom{IRAM00}[mm/dd.dd] & [AU] & [AU] & & & & [km~s$^{-1}$] & [s$^{-1}$] \\ \hline PACS\phantom{00}11/8.74--8.82 & 3.35 & 3.70 & H$_2$O(2$_{12}$--1$_{01}$)\tablefootmark{a} & ${<}2.2\times 10^{-18}$\tablefootmark{a} & W m$^{-2}$ & -- & ${<}1.4\times10^{28}$\\ \hline SPIRE\phantom{0}11/6.59--6.68 & 3.34 & 3.65 & H$_2$O(1$_{11}$--0$_{00}$) & ${<}8\times 10^{-18}$ & W m$^{-2}$ & -- & ${<}4\times10^{28}$ \\ \hline Nan\c{c}ay\phantom{0}02/10--04/19 & 3.27 & 3.90 & OH 18 cm & $-0.016\pm0.003$ & Jy~km~s$^{-1}$ & $-0.32\pm0.12$ & $3.8\pm0.9\times10^{28}$ \\ \hline IRAM\phantom{00}09/13.88 & 3.20 & 2.57 & HCN(1--0) & \phantom{$-$}$0.271\pm0.015$ & K~km~s$^{-1}$\tablefootmark{b} & $-0.21\pm0.03$ & $1.6\pm0.1\times10^{26}$\\ \phantom{IRAM00}09/13.93 & 3.20 & 2.57 & HCN(3--2) & \phantom{$-$}$0.961\pm0.140$ & &$-0.15\pm0.06$ & $1.8\pm0.3\times10^{26}$\\ \phantom{IRAM00}09/14.86 & 3.20 & 2.59 & HCN(1--0) & \phantom{$-$}$0.262\pm0.013$ & &$-0.10\pm0.03$ & $1.6\pm0.1\times10^{26}$\\ \phantom{IRAM00}09/14.93 & 3.20 & 2.59 & HCN(3--2) & \phantom{$-$}$0.972\pm0.097$ & &$+0.03\pm0.04$ & $1.6\pm0.2\times10^{26}$\\ \phantom{IRAM00}09/14.88 & 3.20 & 2.59 & CO(2--1) & \phantom{$-$}$0.433\pm0.028$ & &$-0.04\pm0.03$ & $3.9\pm0.3\times10^{28}$ \\ \phantom{IRAM00}09/14.40 & 3.20 & 2.58 & CH$_3$OH($1_0$--$1_{-1}$E)\tablefootmark{c} & \phantom{$-$}$0.086\pm0.011$ & &$-0.10\pm0.04$ & $1.5\pm0.3\times10^{27}$ \\ \phantom{IRAM00}09/14.93 & 3.20 & 2.59 & H$_2$S($1_{10}$--1$_{01}$) & \phantom{$-$}$0.311\pm0.031$ & &$-0.05\pm0.04$ & $1.0\pm0.1\times10^{27}$ \\ \phantom{IRAM00}09/14.95 & 3.20 & 2.59 & CS(2--1) & \phantom{$-$}$0.028\pm0.012$ & & -- &$0.5\pm0.2\times10^{26}$ \\ \phantom{IRAM00}09/14.95 & 3.20 & 2.59 & H$_2$CO($3_{12}$--$2_{11}$) & ${<}0.203$ & & -- &${<}1\times10^{27}$ \\ \phantom{IRAM00}10/29.71 & 3.32 & 3.48 & HCN(1--0) & \phantom{$-$}$0.165\pm0.010$ & &\phantom{$-$}$-0.15\pm0.03$ & $1.4\pm0.1\times10^{26}$\\ \phantom{IRAM00}10/29.71 & 3.32 & 3.48 & CO(2--1) & \phantom{$-$}$0.248\pm0.026$ & &\phantom{$-$}$-0.11\pm0.03$ & $3.0\pm0.3\times10^{28}$ \\ \hline \end{tabular}\vspace*{-2mm} \tablefoot{\tablefoottext{a}{3-$\sigma$ upper limit per pixel in the central $9.4\arcsec \times 9.4\arcsec$~pixel. The upper limit on the flux per beam is estimated to be $\sim$2 times higher. Upper limits for H$_2$O 2$_{21}$--1$_{10}$, 3$_{13}$--2$_{02}$, 2$_{21}$--2$_{12}$, and 3$_{03}$--2$_{12}$ lines are 4.9, 1.8, 1.0, and 3.9 ($\times$10$^{-18}$) W m$^{-2}$ respectively.} \tablefoottext{b}{For IRAM data, the intensity scale is the main beam brightness temperature.} \tablefoottext{c}{CH$_3$OH $2_0-2_{-1}$E, $3_0-3_{-1}$E, $4_0-4_{-1}$E, $5_0-5_{-1}$E, and $6_0-6_{-1}$E lines were also observed with line intensities of $0.083$, $0.062$, $0.049$, $0.043$, and $0.022$ ($\pm0.010$)~K~km~s$^{-1}$, respectively.}}\vspace*{-2mm} \end{table}