Table 1
All reactions with negative γ coefficients that were refitted.
| Educts | Products | α old | β old | γ old | T min | T max | α new | β new | γ new | [Error] | |||||
|
|
|||||||||||||||
| C | + | O2 | → | CO | + | O | 2.48(–12) | 1.54 | –613 | 295 | 8000 | 9.94(–12) | 1.05 | –42.48 | –0.42, 0.26 |
| N | + | OH | → | NO | + | H | 4.06(–11) | 0.05 | –78 | 103 | 2500 | 5.73(–11) | –0.15 | 1.34 | –0.19, 0.09 |
| NH | + | NH | → | NH2 | + | N | 1.03(–14) | 3.07 | –1123 | 300 | 3000 | 1.81(–13) | 1.80 | –70.03 | –0.47, 0.36 |
| NH | + | NO2 | → | N2O | + | OH | 1.44(–13) | 0 | –1140 | 200 | 300 | 1.06(–11) | –5.36 | 168 | –0.07, 0.04 |
| CH3 | + | NH2 | → | CH2 | + | NH3 | 4.76(–17) | 5.77 | –151 | 300 | 2000 | 4.07(–17) | 5.85 | –205 | –0.03, 0.03 |
| O | + | NH2 | → | HNO | + | H | 4.56(–11) | 0 | –10 | 200 | 3000 | 4.72(–11) | –0.02 | 0.38 | –0.01, 0.01 |
| O | + | OH | → | O2 | + | H | 1.77(–11) | 0 | –178 | 158 | 5000 | 3.35(–11) | –0.28 | 4.30 | –0.29, 0.15 |
| O | + | O2H | → | O2 | + | OH | 3.17(–11) | 0 | –174 | 200 | 2500 | 5.76(–11) | –0.30 | 7.48 | –0.17, 0.09 |
| O | + | HS | → | SO | + | H | 8.25(–11) | 0.17 | –254 | 298 | 2000 | 1.74(–10) | –0.20 | 5.70 | –0.12, 0.06 |
| O | + | NO2 | → | O2 | + | NO | 6.5(–12) | 0 | –120 | 200 | 2500 | 9.82(–12) | –0.21 | 5.16 | –0.12, 0.06 |
| NH2 | + | OH | → | H2O | + | NH | 7.78(–13) | 1.50 | –230 | 250 | 3000 | 1.35(–12) | 1.25 | –43.45 | –0.14, 0.07 |
| OH | + | C2H2 | → | CO | + | CH3 | 6.51(–18) | 4.00 | –1006 | 500 | 2500 | 4.75(–17) | 3.16 | –128 | –0.18, 0.10 |
| OH | + | H2CO | → | HCO | + | H2O | 2.22(–12) | 1.42 | –416 | 200 | 3000 | 7.76(–12) | 0.82 | –30.62 | –0.35, 0.21 |
| OH | + | HNO | → | NO | + | H2O | 4.44(–12) | 1.37 | –169 | 298 | 4000 | 6.17(–12) | 1.23 | –44.29 | –0.09, 0.04 |
| OH | + | O2H | → | O2 | + | H2O | 3.66(–11) | –0.13 | –244 | 200 | 2500 | 8.58(–11) | –0.56 | 14.76 | –0.23, 0.13 |
| NH3 | + | CN | → | HCN | + | NH2 | 3.41(–11) | –0.90 | –9.90 | 25 | 761 | 3.73(–11) | –1.08 | 10.00 | –0.23, 0.09 |
| C2H | + | C2H2 | → | H2CCCC | + | H | 1.31(–10) | 0 | –25 | 143 | 3400 | 1.44(–10) | –0.05 | 0.80 | –0.05, 0.02 |
| CN | + | CH3CH3 | → | C2H5 | + | HCN | 4.8(–12) | 2.08 | –484 | 185 | 1140 | 2.34(–11) | 1.02 | –34.95 | –0.28, 0.17 |
| CN | + | O2 | → | NO | + | CO | 5.01(–12) | –0.46 | –8 | 13 | 1565 | 5.12(–12) | –0.49 | –5.16 | –0.11, 0.02 |
| CN | + | O2 | → | OCN | + | O | 1.86(–11) | –0.13 | –40 | 13 | 4526 | 2.02(–11) | –0.19 | –31.91 | –0.30, 0.07 |
| CN | + | NO2 | → | NO | + | OCN | 3.93(–11) | 0 | –199 | 297 | 2500 | 7.02(–11) | –0.27 | 8.27 | –0.11, 0.06 |
| C2H3 | + | O2 | → | H2CO | + | HCO | 4.62(–12) | 0 | –171 | 200 | 362 | 8.87(–12) | –0.73 | 22.67 | –0.02, 0.01 |
| C2H3 | + | O2 | → | O2H | + | C2H2 | 2.16(–14) | 1.61 | –193 | 300 | 3500 | 3.15(–14) | 1.45 | –51.97 | –0.09, 0.04 |
| HCO | + | O2 | → | O2H | + | CO | 1.58(–12) | 1.24 | –353 | 200 | 2500 | 4.64(–12) | 0.70 | –25.61 | –0.29, 0.17 |
| O2 | + | S | → | SO | + | O | 4.74(–13) | 1.41 | –439 | 200 | 3460 | 1.76(–12) | 0.81 | –30.75 | –0.38,0.24 |
Notes. The coefficients on the left are the original UDFA values, the new fits to the coefficients are given on the right side (numbers in parentheses mean: times ten raised to that power). The last column gives the relative error brackets across the given temperature range (given in K) with respect to the original fit.
Current usage metrics show cumulative count of Article Views (full-text article views including HTML views, PDF and ePub downloads, according to the available data) and Abstracts Views on Vision4Press platform.
Data correspond to usage on the plateform after 2015. The current usage metrics is available 48-96 hours after online publication and is updated daily on week days.
Initial download of the metrics may take a while.