Fig. 2
Section of the millimeter-wave spectrum of
n-C4H9CN displaying features caused by all
three conformers investigated in the present analysis. The
quantum numbers for the
J = 38−37 transitions of the AA conformer are
given in blue (the Kc quantum numbers
have been omitted because the asymmetry splitting was not resolved for these
transitions). Transitions of the GA and AG
conformers have been marked with triangles pointing upward (green) and downward
(red), respectively. Triangles in parentheses are used for overlapped lines or lines
with bad line shape. The AG lines have J = 34−33,
and Ka = 27, 4, and 28 from left to
right;
Kc = J − Ka + 1
for the Ka = 4 line. The
GA lines belong to b-type
Q-branch transitions with quantum numbers
JKa,Kc = 409,31−408,32,
697,62−696,63, and 9511,84−9510,85
from left to right. The lines are presented as second derivatives of a Gaussian line
shape because of the 2f-modulation.
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