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Table 9
Dominant reactions of observed and intermediate species following CH4 sublimation.
| C2H2: | |||||||
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|
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| 1.) | C + | + | CH4 | → | C2![]() |
+ | H |
| 2.) | C2![]() |
+ | e | → | C2H2 | + | H |
| 3.) | C + | + | CH4 | → | C2![]() |
+ | H2 |
| 4.) | C2![]() |
+ | H2 | → | C2![]() |
||
| 5.) | C2![]() |
+ | e | → | C2H2 | + | 2 H |
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| C3H3: | |||||||
|
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| 6.) | C2![]() |
+ | CH4 | → | C3![]() |
+ | H2 |
| 7.) | C2![]() |
+ | CH4 | → | C3![]() |
+ | H |
| 8.) | C3![]() |
+ | e | → | C3H3 | + | H2 |
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C3 : |
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|
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| 9.) | C | + | C2H2 | → | C3H | + | H |
| 10.) | HCO+ | + | C3 | → | C3H+ | + | CO |
| 11.) | C + | + | C2H2 | → | C3H+ | + | H |
| 12.) | HCO+ | + | C3H | → | C3![]() |
+ | CO |
| 13.) | C3H+ | + | H2 | → | C3![]() |
+ | H |
| 14.) | C3![]() |
+ | CH4 | → | C3![]() |
+ | CH3 |
| 15.) | HCO+ | + | c-C3H2 | → | C3![]() |
+ | CO |
| 16.) | C3H+ | + | H2 | → | C3![]() |
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| CCH: | |||||||
|
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| 17.) | C2![]() |
+ | e | → | CCH | + | 2 H |
| 18.) | HCO+ | + | CCH | → | C2![]() |
+ | CO |
|
|
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| C3: | |||||||
|
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| 19.) | C | + | C2H2 | → | C 3 | + | H2 |
| 20.) | CCH | + | C 3 | → | C5 | + | H |
|
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| c-C3H2: | |||||||
|
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| 21.) | H | + | C3H3 | → | c-C3H2 | + | H2 |
| 22.) | C3![]() |
+ | e | → | c -C 3 H 2 | + | H |
| 23.) | CH | + | C2H2 | → | c-C3H2 | + | H |
| 24.) | HCO+ | + | c-C3H2 | → | C3![]() |
+ | CO |
Notes. The observed species are identified in bold type.
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