Notes. Column entries are: (1) VFTS identifier; (2) spectral classification; (3) binary status (from Dunstall et al., in prep.) (4) Hα morphology: “a” = (photospheric) absorption, “e” = (stellar) emission; “f” = flat, with no indication of the nature of the line profiles outside the region of nebular emission (i.e. no strong, broad emission); “q” = P-Cygni profile (used classically to distinguish from a “p” suffix, which simply indicates peculiar); (5) and (6) V and B − V photometry from Paper I; (7) and (8) estimated radial velocity (v_r) and standard deviation (σ); (9) method/lines used to estimate v_r: “1” and “2” refer to the lines listed in Table 3, “3” indicates the three stars for which other metal lines were used, “B” indicates that the estimate is the mean value from the multi-epoch data available (see Sect. 4.2, with the limitations of these as estimates of the centre-of-mass velocities discussed in Sect. A.3); (10) alternative identifiers used in the literature; (11) previous classifications and other relevant comments. Aliases/past classifications are from: R/F60 (Feast et al. 1960); AL (Andrews & Lindsay 1964); Sk (Sanduleak 1970); BE74 (Bohannan & Epps 1974); BI (Brunet et al. 1975); W84 (Walborn 1984); Mk (Melnick 1985); W86 (Walborn 1986); T88 (Testor et al. 1988); ST92 (Schild & Testor 1992); P93 (Parker 1993); WB97 (Walborn & Blades 1997); B99 (Bosch et al. 1999). The crosschecks with the catalogues from Andrews & Lindsay (1964) and Bohannan & Epps (1974) employed the updated astrometry from Howarth (2012, 2013).