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Table A.2
Maximum impact parameters, and thermal rate and equilibrium constants as a function of the temperature of the isotope-exchange reactions (3) and (5).
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|---|---|---|---|---|
| T∕K | bmax/Å | k3/cm3 molecule−1 s−1 | k-3/cm3 molecule−1 s−1 | K3/unitless |
| 500.00 | 5.3 | 7.2907 (− 11)(a) | 1.3827 (− 10) | 0.5273 |
| 400.00 | 5.2 | 6.4284 (− 11) | 1.2031 (− 10) | 0.5343 |
| 298.15 | 5.4 | 5.4131 (− 11) | 0.9903 (− 10) | 0.5466 |
| 200.00 | 5.1 | 4.2920 (− 11) | 0.7516 (− 10) | 0.5710 |
| 100.00 | 5.3 | 2.8747 (− 11) | 0.4408 (− 10) | 0.6521 |
| 50.00 | 5.1 | 1.9250 (− 11) | 0.2263 (− 10) | 0.8505 |
| 25.00 | 4.9 | 1.2850 (− 11) | 0.0888 (− 10) | 1.4471 |
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| T∕K | bmax/Å | k5/cm3 molecule−1 s−1 | k-5/cm3 molecule−1 s−1 | K5/unitless |
| 500.00 | 5.2 | 4.9854 (− 12) | 9.5064 (− 12) | 0.5244 |
| 400.00 | 5.2 | 4.4625 (− 12) | 8.4084 (− 12) | 0.5307 |
| 298.15 | 5.2 | 3.8700 (− 12) | 7.1450 (− 12) | 0.5416 |
| 200.00 | 5.1 | 3.1539 (− 12) | 5.5987 (− 12) | 0.5633 |
| 100.00 | 5.2 | 2.1934 (− 12) | 3.4560 (− 12) | 0.6347 |
| 50.00 | 5.0 | 1.5321 (− 12) | 1.9018 (− 12) | 0.8056 |
| 25.00 | 4.9 | 1.0789 (− 12) | 0.8312 (− 12) | 1.2980 |
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