Open Access

Table A.1

Quantum numbersa, transition frequency (Frequency), uncertainty (Unc.), lower state energy (Elow) and A value of OH Λ-doubling transitions in the υ = 0, 2Π3/2 state from our present fit.

N p J F - N Ρ υ J F Frequency (MHz) Unc. (MHz) Elow (cm−1) A (×10−6s−1)
8 + 8.5 8 - 8 - 0 8.5 8 91188.2709 0.0118 1321.2779 0.455
8 + 8.5 9 - 8 - 0 8.5 9 91203.2537 0.0119 1321.2763 0.455
9 - 9.5 9 - 9 + 0 9.5 9 113605.1955 0.0225 1650.8123 0.691
9 - 9.5 10 - 9 + 0 9.5 10 113621.0752 0.0226 1650.8106 0.692
10 + 10.5 10 - 10 - 0 10.5 10 137959.2898 0.0400 2015.0501 1.00
10 + 10.5 11 - 10 - 0 10.5 11 137975.8958 0.0400 2015.0483 1.00
11 - 11.5 11 - 11 + 0 11.5 11 164119.0489 0.0671 2413.6161 1.38
11 - 11.5 12 - 11 + 0 11.5 12 164136.2367 0.0670 2413.6143 1.38
12 + 12.5 12 - 12 - 0 12.5 12 191954.3152 0.1069 2846.0782 1.84
12 + 12.5 13 - 12 - 0 12.5 13 191971.9613 0.1068 2846.0764 1.84
13 - 13.5 13 - 13 + 0 13.5 13 221334.0293 0.1633 3311.9534 2.39
13 - 13.5 14 - 13 + 0 13.5 14 221352.0274 0.1633 3311.9515 2.39
14 + 14.5 14 - 14 - 0 14.5 14 252124.9162 0.2410 3810.7117 3.03
14 + 14.5 15 - 14 - 0 14.5 15 252143.1736 0.2409 3810.7097 3.03
15 - 15.5 15 - 15 + 0 15.5 15 284190.8005 0.3451 4341.7799 3.76
15 - 15.5 16 - 15 + 0 15.5 16 284209.2356 0.3450 4341.7779 3.76
16 + 16.5 16 - 16 - 0 16.5 16 317392.3410 0.4823 4904.5444 4.58
16 + 16.5 17 - 16 - 0 16.5 17 317410.8811 0.4821 4904.5424 4.58
17 - 17.5 17 - 17 + 0 17.5 17 351587.0429 0.6607 5498.3532 5.49
17 - 17.5 18 - 17 + 0 17.5 18 351605.6228 0.6604 5498.3512 5.49
18 + 18.5 18 - 18 - 0 18.5 18 386629.4537 0.8906 6122.5182 6.49
18 + 18.5 19 - 18 - 0 18.5 19 386648.0141 0.8904 6122.5161 6.49
19 - 19.5 19 - 19 + 0 19.5 19 422371.4796 1.1855 6776.3171 7.56
19 - 19.5 20 - 19 + 0 19.5 20 422389.9664 1.1852 6776.3150 7.56
20 + 20.5 20 - 20 - 0 20.5 20 458662.7788 1.5620 7458.9951 8.71
20 + 20.5 21 - 20 - 0 20.5 21 458681.1420 1.5616 7458.9930 8.71
21 - 21.5 21 - 21 + 0 21.5 21 495351.2024 2.0407 8169.7667 9.91
21 - 21.5 22 - 21 + 0 21.5 22 495369.3956 2.0403 8169.7645 9.91
22 + 22.5 22 - 22 - 0 22.5 22 532283.2601 2.6460 8907.8168 11.2
22 + 22.5 23 - 22 - 0 22.5 23 532301.2398 2.6454 8907.8147 11.2
23 - 23.5 23 - 23 + 0 23.5 23 569304.5950 3.4052 9672.3031 12.5
23 - 23.5 24 - 23 + 0 23.5 24 569322.3204 3.4046 9672.3010 12.5
24 + 24.5 24 - 24 - 0 24.5 24 606260.4552 4.3480 10462.3568 13.8
24 + 24.5 25 - 24 - 0 24.5 25 606277.8875 4.3473 10462.3546 13.8

Notes. (a) N is the rotational quantum number, p is the parity, J and F are the resulting momenta after adding the electron and nuclear spin angular momenta to the rotational one; ν is the vibrational state.

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