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Table A.2

Quantum numbersa, transition frequency (Frequency), uncertainty (Unc.), lower state energy (Elow) and A value of OH Λ-doubling transitions in the υ = 0, 2Π1/2 state from our present fit.

N p J F - N p υ J F Frequency (MHz) Unc. (MHz) Elow (cm−1) A (×10−6s−1)
11 - 10.5 11 - 11 + 0 10.5 11 85665.9971 0.0267 2450.2579 0.105
11 - 10.5 10 - 11 + 0 10.5 10 85703.3790 0.0268 2450.2553 0.105
12 + 11.5 12 - 12 - 0 11.5 12 107036.8197 0.0438 2880.4897 0.179
12 + 11.5 11 - 12 - 0 11.5 11 107073.0719 0.0441 2880.4872 0.179
13 - 12.5 13 - 13 + 0 12.5 13 130078.2350 0.0701 3344.4717 0.281
13 - 12.5 12 - 13 + 0 12.5 12 130113.4391 0.0705 3344.4691 0.281
14 + 13.5 14 - 14 - 0 13.5 14 154660.6445 0.1087 3841.6102 0.418
14 + 13.5 13 - 14 - 0 13.5 13 154694.8639 0.1093 3841.6077 0.419
15 - 14.5 15 - 15 + 0 14.5 15 180652.6153 0.1643 4371.2832 0.594
15 - 14.5 14 - 15 + 0 14.5 14 180685.8990 0.1650 4371.2806 0.594
16 + 15.5 16 - 16 - 0 15.5 16 207920.2054 0.2433 4932.8383 0.811
16 + 15.5 15 - 16 - 0 15.5 15 207952.5907 0.2440 4932.8358 0.812
17 - 16.5 17 - 17 + 0 16.5 17 236326.7051 0.3548 5525.5932 1.07
17 - 16.5 16 - 17 + 0 16.5 16 236358.2198 0.3557 5525.5907 1.07
18 + 17.5 18 - 18 - 0 17.5 18 265732.6519 0.5115 6148.8354 1.38
18 + 17.5 17 - 18 - 0 17.5 17 265763.3164 0.5123 6148.8329 1.38
19 - 18.5 19 - 19 + 0 18.5 19 295996.0281 0.7297 6801.8227 1.74
19 - 18.5 18 - 19 + 0 18.5 18 296025.8563 0.7305 6801.8203 1.74
20 + 19.5 20 - 20 - 0 19.5 20 326972.5743 1.0298 7483.7842 2.14
20 + 19.5 19 - 20 - 0 19.5 19 327001.5751 1.0306 7483.7818 2.14
21 - 20.5 21 - 21 + 0 20.5 21 358516.1794 1.4363 8193.9209 2.59
21 - 20.5 20 - 21 + 0 20.5 20 358544.3573 1.4370 8193.9184 2.59
22 + 21.5 22 - 22 - 0 21.5 22 390479.3150 1.9770 8931.4066 3.07
22 + 21.5 21 - 22 - 0 21.5 21 390506.6708 1.9776 8931.4042 3.07
23 - 22.5 23 - 23 + 0 22.5 23 422713.4928 2.6823 9695.3897 3.60
23 - 22.5 22 - 23 + 0 22.5 22 422740.0243 2.6828 9695.3873 3.60
24 + 23.5 24 - 24 - 0 23.5 24 455069.7308 3.5839 10484.9933 4.16
24 + 23.5 23 - 24 - 0 23.5 23 455095.4332 3.5843 10484.9910 4.16

Notes. (a) N is the rotational quantum number, p is the parity, J and F are the resulting momenta after adding the electron and nuclear spin angular momenta to the rotational one; υ is the vibrational state.

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