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Table 2.
Rotational constants of v12 = 1, and v9 = 1 excited vibrational states of the parent isotopolog of thioformamide.
| Parameters | v12 = 1 | v9 = 1 |
|---|---|---|
| A (MHz) | 61118.626(83) (a) | 61890.776(81) |
| B (MHz) | 6098.12788(52) | 6101.04527(57) |
| C (MHz) | 5552.46610(25) | 5544.50067(27) |
| ΔJ (kHz) | 2.608050(46) | 2.582672(44) |
| ΔJK (kHz) | −48.371(17) | −47.945(17) |
| ΔK (kHz) | 1433.5(12) | 1561.6(16) |
| δJ (kHz) | 0.377740(70) | 0.377563(72) |
| δK (kHz) | 16.3958(97) | 18.7564(88) |
| ΦJ (Hz) | 0.0019722(68) | 0.0019123(65) |
| ΦJK (Hz) | −0.02115(16) | −0.01684(19) |
| ΦKJ (Hz) | −4.9201(99) | −5.961(12) |
| ϕJ (Hz) | 0.000670(14) | 0.000648(13) |
| LKKJ (mHz) | 0.423(19) | 0.450(25) |
| ΔE (MHz)/(cm−1) | 1798505.8(17)/59.991696(57) | |
| Ga (MHz) | 25010.4(24) | |
 (MHz) |
0.00665(59) | |
| Gb (MHz) | −829.39(51) | |
 (MHz) |
0.003478(42) | |
| N(b) | 690 | 686 |
| σ (MHz) (c) | 0.028 | 0.027 |
| σw(d) | 0.68 | 0.64 |
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