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Table 2

Overview of the various models investigated in this work.

Model ERa PDIb 3Bc 3BEFd No. rounds RD efficiency H2 removal Other modifications
I1 Exp. based
I2 Exp. based Tunnel diffusion
I3 Exp. based Fast diffusion

I4 Exp. based Scaled Eb
I5 Exp. based Scaled Eb Tunnel diffusion
I6 Exp. based Scaled Eb Fast diffusion

D1 1% Scaled Eb
D2 1% Scaled Eb Tunnel diffusion
D3 1% Scaled Eb Fast diffusion

ND1 1% Scaled Eb
ND2 1% Scaled Eb
ND3 1 1% Scaled Eb
ND4 2 1% Scaled Eb
ND5 1 1% Scaled Eb
ND6 1 1% Scaled Eb

D4 1% Scaled Eb

ND7 1% Scaled Eb
ND8 1% Scaled Eb
ND9 1 1% Scaled Eb
ND10 2 1% Scaled Eb
ND11 1 1% Scaled Eb
ND12 1 1% Scaled Eb

NM1 1% Scaled Eb Include CH3O+H2CO
NM2 1 1% Scaled Eb Include CH3O+H2CO

BE1 1% Eb(H2) = 640/500e K
BE2 1% Dynamic Eb all species
BE3 1% Dynamic Eb only H2
BE4 1% Dynamic Eb only H & H2

D5 1% Scaled Eb H-abstraction reac.
D6 Exp. based Scaled Eb
D7 Exp. based Scaled Eb H-abstraction reac.

D8 1% Scaled Eb Ini.abund: 50%H/50%H2

Notes. Only the chemical and physical properties that vary between models are listed. Models that apply the single collision model proposed by Hasegawa et al. (1992) to derive the reaction probabilities. Models that apply the RDC model proposed by Chang et al. (2007) to derive the reaction probabilities. (a)Eley-Rideal reactions, (b)photodissociation-induced reactions, (c) three-body reactions and (d)three-body reactions with excited formation. IX are models with intermediate modifications steps presented in Appendices A and B, DX are models with solely diffusive reaction mechanisms, NDX are models with additional non-diffusive reaction mechanisms, NMX are models for which the chemical network was modified, and BEX are models with modified H2 removal methods. (e) 640 K being the binding energy on bare grain surfaces, 500 K being the binding energy on water ice.

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