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Fig. 9

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Experimental LIF spectrum (red) of the B3ΣuX3Σg(5,0)$\[B^3 \Sigma_u^{{}-} \leftarrow X^3 \Sigma_g^{{}-}(5,0)\]$ band of S2 with a rotational temperature of ~300 K, produced by the photolysis of H2S in a static cell from Green & Western (1996) compared to a spectrum (black) calculated using the refined model with the B′-B coupling effect method from this work.

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