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Table 2
Values of the χ factor parameters for CO2 mixtures defined in Table 1.
| ν2 band (≈667 cm−1) | ν3 band (≈2349 cm−1) | ν1 + ν3 band (≈3737 cm−1) | |||||||
|---|---|---|---|---|---|---|---|---|---|
| CO2-CO2 | α | β | γ | α | β | γ | α | β | γ |
| B1 | 0.085 | 1.962 | 0.02 | 0.055 | −0.11 | 0.008 | 0.034 | −0.4 | 0.0162 |
| B2 | 0.0185 | − | − | 0.021 | 0.08 | 0.0095 | 0.016 | 2174.3 | 0.057 |
| B3 | 0.011 | − | − | 0.01 | − | − | 0.01 | − | − |
| CO2-N2 | α | β | γ | α | β | γ | α | β | γ |
| B1 | 0.065 | 0.038 | 0.003 | 0.416 | −0.354 | 0.00386 | 0.02 | −0.354 | 0.0386 |
| B2 | 0.018 | 0.055 | 0.02 | 0.0167 | 0.0421 | 0.00248 | 0.33 | 0.0421 | 0.00248 |
| B3 | 0.0085 | − | − | 0.019 | − | − | 0.019 | − | − |
| CO2-H2O | α | β | γ | α | β | γ | α | β | γ |
| B1 | − | − | − | 0.075 | −0.02589 | 0.00344 | − | − | − |
| B2 | − | − | − | 0.024 | −0.0166 | 0.00199 | − | − | − |
| B3 | − | − | − | 0.0025 | − | − | − | − | − |
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