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Table 3

Classification of molecular species based on their response to cosmic-ray ionization rates, temperatures, and densities.

Species group Abundance behavior Diagnostic use
CS, SO, SiO, HCN, HNC, CH3CN Minimal variations across ζ in all environments Potentially can act as normalizers for abundance ratios
HCO+, H2CO, CH3SH Systematic changes as function of ζ across all environments; HCO+ increases, others decrease with ζ Best suited as ζ tracers
HCO, HNCO, CH3CHO Systematic, decreasing trends in protostellar objects as function of ζ Potentially useful as ζ tracers in protostellar environments
NS+, C2S, HC3N, CH2CO, CH3OH, CH3SH, NH2CHO, CH3CCH, CH3CHO, CH3NCO, HCOOCH3, C2H5CN, C2H5OH, CH3OCH3 Significant abundance changes in protostellar objects at ζ ≳ 10−14 s−1; consistent behavior in shocks Differentiate shocked vs. protostellar environments at high ζ
NS+, CH2CO, CH3OH, CH3SH, NH2CHO HCOOCH3 ~300 K is a turning point – more pronounced difference between protostellar objects and shocks or behavioral patterns shifts Selective sensitivity to temperature
HCO, HCO+, CH3SH, CH3NCO, HCOOCH3 Consistent trends across a broad range of temperatures discriminating the gas types Differentiate shocked vs. protostellar environments based on temperature
NS+, CH3SH, CH3CHO, CH3NCO Abundance always <10−7: NS+ in protostellar objects and post-shocked gas; CH3SH, CH3CHO in protostellar objects; CH3NCO in shocks Environmental abundance constraints

Notes. *Species for which the significant abundance changes lead to falling below the detectability threshold (X < 10−14). We discuss this in more detail in Sect. 4.1.1.

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