Open Access
Issue
A&A
Volume 706, February 2026
Article Number A133
Number of page(s) 11
Section Galactic structure, stellar clusters and populations
DOI https://doi.org/10.1051/0004-6361/202555820
Published online 09 February 2026

© The Authors 2026

Licence Creative CommonsOpen Access article, published by EDP Sciences, under the terms of the Creative Commons Attribution License (https://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.

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1 Introduction

The fragile light element lithium (Li), with its cosmological and stellar significance in the evolution of the Universe, has been extensively studied throughout the literature. With respect to cosmological constraints, the main issue is related to the persistent discrepancy between the primordial Li abundance and the values derived from metal-poor halo stars. Recent results indicate a primordial Li abundance of 2.69 ± 0.02 (Yeh et al. 2021) and a stellar Li abundance of 2.16 ± 0.07 (Matas Pinto et al. 2021).

In general studies of Galactic Li, significant differences arise depending on the metallicity regime under consideration, with dwarf stars at very low halo metallicities having primarily been associated with studies of the well-known Spite plateau. With respect to giant stars and in relation to the cosmological Li problem, Mucciarelli et al. (2022) found a thin Li plateau at a Li abundance of around 1.0 dex. This plateau, with metallicities between approximately −4.0 and −1.0 formed by lower red giant branch (RGB) stars, differs from that of dwarf stars. However, it points to the same Li value as in dwarfs once dredge-up is accounted for. Presently, we find ourselves in a unique situation in which only a few halo and thick-disc Li-rich giant stars have been discovered, making the study of such stars at very low metallicities a relatively new and open field for research.

Since 2008, several observers have identified new Li-rich field giant stars at very low metallicities, generally referred to as low-mass stars (M < 2 M). These detections include: Roederer et al. (2008); Martell & Shetrone (2013); Ruchti et al. (2011); Roederer et al. (2014); Li et al. (2018); Sitnova et al. (2023); Susmitha et al. (2024); Kowkabany et al. (2024), and Mucciarelli et al. (2024). As noted by these authors, the Li abundances of these giant stars range from 1.6 to 4.8, with [Fe/H] values from −4.0 to −1.4, and log g values from 0.6 to 3.2. A comprehensive catalogue of these stars was compiled by Mucciarelli et al. (2024), listing approximately 30 Li-rich field giant stars with these parameters.

A key physical aspect related to Li-rich giant stars at very low metallicities concerns the mechanism responsible for the production of fresh 7Li. The extent to which these processes are similar to those acting in the higher-metallicity regime ([Fe/H] > −1.0), such as those in the Galactic thin-disc, is a matter of debate. Two main scenarios have been proposed thus far: (1) an internal stellar mechanism based on the well-known Cameron-Fowler (CF) process or (2) an external mechanism involving mass transfer from a more massive companion in a binary system. There is no clear consensus on which scenario is the most plausible. A recent study by Sayeed et al. (2025) examined the different types of binaries that contribute to the Li enhancement. Based on GALAH observations, their main results indicate that binary stars can produce Li-rich giant stars with A(Li) values ranging from 1.5 to 2.2 dex; however, to attain these values, these stars must be enriched in some way to achieve Li abundance values between 2.5 and 3.2 dex during their main sequence stage. Furthermore, to obtain Li-rich or very Li-rich giant stars with Li values greater than 2.2 dex, these stars require additional mechanisms.

Other important parameters discussed in the literature include the scarcity of data on stellar rotation and activity in the very low-metallicity regime. Nevertheless, some recent exceptional discoveries of Li-rich giants provide input for further research in this emerging field. For example, the Li-rich giant with the lowest metallicity discovered so far, HE 0057-5959 (Mucciarelli et al. 2024), has [Fe/H] = −3.95, a Li abundance of 2.05 dex and a log g value of 3.05. Another remarkable case is 2MASS J05241392-0336543, which has a Li abundance of 6.15 dex (Kowkabany et al. 2024) and [Fe/H] = −2.43, making it the most Li-rich giant star detected to date.

In this work, we investigate the evolution of Li-rich giant stars in the halo and thick-disc Galactic regions. Our study is based on two datasets of low-mass giant stars with metallicities between −4.0 and −1.0: (a) a sample of 1703 Li-rich giant stars with Li abundances between 1.5 and 6.15 dex, primarily obtained from the LAMOST DR9 catalogue (Ding et al. 2024), with a few additional stars from the literature; and (b) a dataset of 2468 Li-rich and Li-poor giant stars, resulting from merging the LAMA LAMOST catalogue (Li et al. 2024) for rotational velocity (v sin i) values with the LAMOST DR9 catalogue (Ding et al. 2024) for Li abundances. We conducted a preliminary analysis of the membership of the selected stars in different Galactic subsystems (halo, thick disc, and thin disc) based on Gaia DR3 astrometric data (Gaia Collaboration 2022), metallicity, and the alpha-element-to-iron ratio.

This paper is structured as follows: Section 2 analyses and compares the values of the physical variables used, which were taken from the catalogues compiled by Ding et al. (2024) and Li et al. (2024). It also evaluates and discusses the uncertainties associated with the variables involved in our study and examines the membership of these objects in the different Galactic subsystems. Section 3 discusses the evolutionary status of Li-rich giant stars. Section 4 provides an overview of the Cameron-Fowler model. Section 5 presents a general discussion on stellar rotation. Finally, Sect. 6 offers our conclusions and a summary.

2 Sample analysis: Bias, errors, and kinematic classification

2.1 Bias and errors

Our analysis is based mainly on the LAMOST DR9 catalogue published by Ding et al. (2024). This survey contains information on the parameters [Fe/H], log(g), Teff, RV, and A(Li), and it is available in Vizier under the reference

J/ApJS/271/58/table1
. Only the Li abundance has associated parameters that quantify both the precision and the uncertainty of the values, in comparison with the set of standards adopted and other previous catalogues derived from LAMOST spectra. We adopted the variable
e_DelA(Li)
as a reasonable estimate of the uncertainty in the Li abundance. Its median value calculated for our total number of 3537 stars is 0.1 with a SD of 0.3. The projected stellar rotational velocities, V sin i, were taken from Li et al. (2024). This catalogue is also based on the LAM-OST medium-resolution spectra (MRS), as in Ding et al. (2024). Both catalogues provide [Fe/H], Teff, log(g), and RV values, derived through different methodologies and, crucially, using different sets of calibration stars. Li et al. (2024) also provides an individual uncertainty estimate of V sin i for each object. The availability of two catalogues with stellar parameters derived from the same set of spectra allows us to estimate statistical indicators that quantify the uncertainty of the parameters used in this study; specifically, those from Ding et al. (2024). Cross-matching both catalogues for our target sample yields 2465 stars in common. The statistical estimators used are defined below, with the resulting values given in Table 1.
  • ∆ Sys – median of the difference between the value in Ding et al. (2024) and that in Li et al. (2024);

  • MAD – median of the absolute value of the difference, corrected for the estimated bias;

  • σcrit – dispersion calculated as 1.4826 × MAD, assuming a Gaussian distribution;

  • % outliers – fraction of stars whose absolute bias-corrected difference exceeds 3 σcrit;

  • σinternal – median of the individual uncertainty reported by Li et al. (2024).

These results show that discrepancies arising from the use of different pipelines and calibration standards introduce greater uncertainties than individual random errors associated with the spectra quality and data reduction methodology. The largest systematic offsets are found for metallicity and radial velocity. The projected rotational velocity, V sin i, comes directly from Li et al. (2024), along with an individual uncertainty estimate for each object. The median of these uncertainties is 1.76 km s−1. For the kinematic analysis, we used stellar distances, proper motions, and radial velocities. Distances were taken from Bailer-Jones et al. (2021), proper motions from Gaia DR3, and RVs from Ding et al. (2024). Distances and proper motions have individual uncertainty estimates. For all stars, we adopted an RV uncertainty of 7 km s−1, based on the bias between the two catalogues and a representative value of the combined systematic and random errors (see Table 1). Assuming quadratic error propagation, we derived the distribution of relative velocity errors, finding that 90% of the stars in our sample have a relative velocity error below 16%.

Table 1

Comparison of stellar parameters from Ding et al. (2024) and Li et al. (2024) for 2465 common stars.

thumbnail Fig. 1

Diagram of Toomre for the stellar samples used in this work. Green indicates AGB stars, red represents HB stars, and blue corresponds to RGB stars. The two semicircles indicate, as a first approximation, the boundaries between the thin and thick disc (70 km s−1), and between the thick disc and the halo (180 km s−1).

2.2 Sample distribution in the galactic phase space

We distinguished between three different evolutionary stages: RGB stars, horizontal branch (HB) stars, and asymptotic giant branch (AGB) stars. This classification is based on surface gravity (log g), following the methodology of de la Reza (2025, hereafter DLR25) and the asteroseismic study by Yan et al. (2021). Specifically, we applied:

  • RGB stars: 2.8 ≤ log g ≤ 3.5;

  • HB stars: 2.0 ≤ log g < 2.8;

  • AGB stars: 0.3 ≤ log g < 2.0.

Our main objective was to determine the distribution of the three classes of giant stars used in our study across the different Galactic subsystems: thin disc, thick disc, and halo. The ranges of alpha-to-iron abundance ratio, [α/Fe], and metallicity, [Fe/H], further constrained the classification. Nevertheless, it must be noted that this classification method is only an approximation. For instance, it cannot unambiguously distinguish whether a star is an AGB or an upper-RGB star. We obtained the variables (X, Y, Z, U, V, W), referred to the Sun, for the catalogue by Ding et al. (2024, LAMOST-DR9), which contains the chemical abundances A(Li) and [Fe/H], forming the basis of our study. Radial velocities were taken from the same catalogue, while the equatorial ICRS coordinates and proper motions originate from Gaia DR3 (Gaia Collaboration 2022). Distances were taken from Bailer-Jones et al. (2021), based on Gaia EDR3 parallaxes (Gaia Collaboration 2020). The transformation to a Galactocentric reference frame was carried out assuming R0 = 8.2 kpc, a solar rotation velocity of VLSR = 232 km s−1 (McMillan 2017) and a peculiar solar motion of (U0, V0, W0) = (5.0, 17.5, 6.46) km s−1, determined from the kinematics of cool giant stars (Ayari & Elsanhoury 2024). With these values, we computed the Galactocentric spatial coordinates (Xgc, Ygc, Zgc) and the cylindrical velocity components with respect to the Galactic centre (VR, Vϕ, VZ).

Using this information, we present a Toomre diagram (see Fig. 1), where the classes defined by intervals of log g appear in green (AGB), red (HB), and blue (RGB). Semicircles indicating approximate boundaries between the three Galactic components present in the sample are overplotted. The boundary between the thin and thick disc is set at 70 km s−1, while the boundary between thick disc and halo is set at 180 km s−1 (Mardini et al. 2022).

Here, [α/Fe] as a function of [Fe/H] is shown in Fig. 2. The [α/Fe] values are taken from Zhang et al. (2024), while [Fe/H] is from Ding et al. (2024). As expected for halo and thick-disc stars, [α/Fe] is generally positive. It is interesting to note the presence of some negative values, indicating a deficiency in α-elements across the entire low metallicity range. The most plausible interpretation for these α-deficient giant stars is contamination by α-poor supernovae of Type Ia and pure core-collapse events (Jeena & Banerjee 2024).

According to these data, we obtained the following classification: halo (74%), thick disc (22%), and thin disc (4%). The stars associated with the thin-disc appear to belong to the so-called metal-poor thin-disc (or Atari disc, Mardini et al. 2022), with some having [α/Fe] and [Fe/H] values suggestive of a primordial thin-disc origin. Figure 1 shows no significant difference between the three evolutionary stages of the giants. However, the spatial distribution of these objects in Galactocentric cylindrical coordinates (|Z|, ωGC) (see Fig. 3) reveals a well-defined pattern in which the spatial extent of each class increases with decreasing log g, as expected since the luminosity of giants increases with decreasing log g for the selected sample. In summary, there appears to be no underlying metallicity pattern in either the Toomre diagram or the spatial distribution of the objects in our samples.

thumbnail Fig. 2

[α/Fe] versus [Fe/H]. Most of the stars are concentrated around [α/Fe] = 0.23 (median) with a σ = 0.07. Green indicates AGB stars, red represents HB stars, and blue corresponds to RGB stars.

3 The stellar evolutionary stages of Li-rich giant stars

The exploration of the Galactic halo provides insight into the subsequent generations of the first stars in the Galaxy. These very old stars are considered fossil records of early chemical enrichment. Although the primordial light element Li is a key component of these stars, investigations of carbon, the first heavy element synthesised after the Big Bang, have also driven the study of early chemical enrichment. However, these very metal-poor stars are challenging to detect because of their rarity, representing only about 0.1% of all stars in the Galaxy (Yao et al. 2024, and references therein).

The extreme scarcity of stars in the metallicity range −4.0 ≤ [Fe/H] ≤ −3.0 is evident in the Galactic maps by Chiti et al. (2021, see their Fig. 3). In recent years, searches based on spectroscopy and photometry have identified only a modest number of stars within the metallicity range approximately −4.0 to −2.0. It is only with large-scale surveys such as Gaia (photometry) and LAMOST and APOGEE (metallicity) that these searches were significantly advanced. Thanks to these large datasets, extensive catalogues of halo RGB stars (Viswanathan et al. 2024) and very metal-poor stars (Yao et al. 2024) have been compiled.

Figure 4 presents the distribution of all stellar data with [Fe/H] ≤ −1.0 used in this work, showing the Li abundance as a function of Teff for the catalogue of Ding et al. (2024). AGB stars (green), HB stars (red), and RGB stars (blue) exhibit a clear relationship to Teff for stars cooler than 6000 K. Notably, this dataset aligns well with our sample of halo and thick-disc stars.

The detection of Li-rich giant stars in the extreme metallicity range −4.0 ≤ [Fe/H] ≤ −3.0 is even more challenging, as these objects only account for ∼1.0% of normal Li-poor giants in the thin disc (see DLR25). The most important catalogues of giant stars are represented by the LAMOST and GALAH catalogues, which have included Li abundances; in LAMOST, other parameters such as the projected stellar rotation velocities are also provided. This new data has enormously changed our panorama on field low-mass giant stars.

Among the LAMOST catalogues discussed in this work, the first important resource is that work of Gao et al. (2019), based on low-resolution spectra. A new version later appeared, based on medium-resolution spectra, published in Gao et al. (2021). Both studies used a minimum Li abundance of 1.5 dex to characterise a Li-rich giant star. In 2024, two additional catalogues based on medium-resolution spectra were released: the LAMA LAMOST catalogue (Li et al. 2024), which introduced the stellar rotation values, v sin i, and the LAMOST DR9 catalogue (Ding et al. 2024), which significantly expanded the number of targets. These last two catalogues were used in this work. Here, we present a comparison between the data from Ding et al. (2024) and Gao et al. (2021) to highlight important differences related to physical features reported in Gao’s catalogues.

First, concerning the Li abundance values, both catalogues reveal a similar behaviour in the interval corresponding to those of Li-rich giant stars. The only exception corresponds to very low Li abundances, namely, less than −1 (noting this exception is not shown in these figures). This means that the important Li abundance values derived from both catalogues are similar. In Fig. 5a, we show a representation of the Li abundance of field giant stars as a function of log g for both catalogues: that of Gao et al. (2021) in red and that of Ding et al. (2024) in blue. In general, both distributions present the same patterns, even considering the quite different numbers of stars involved. However, concerning giant stars that occupy the log g interval between log g values near 0.3 up to 3.5, an important difference appears between log g at 2.8 and that at 3.5, which coincides with our classified RGB stars. Specifically, in this interval, Ding’s RGB stars are much more numerous than those corresponding to Gao’s. In other words, RGB stars in Ding’s distribution present many more Li-rich giant stars than those in Gao’s distribution. The same differences appear for AGB stars defined between log g values of 0.3 and 2.0. However, it is noteworthy that HB stars defined around the log g value of 2.5 present similar distributions in both catalogues. The consequence of the aforementioned difference in the interval corresponding to RGB stars is as follows. Yan et al. (2021) and DLR25, which worked with Gao’s catalogues for higher metallicities corresponding to those of the Galactic thin-disc, found that only RGB stars present a maximum Li abundance near the value of 2.6 dex. If we go on to consider the previously mentioned large difference in RGB stars of both catalogues, we can infer that working with Ding’s catalogue, this low Li abundance will no longer be valid and RGB stars will attain very large Li abundances similar to those of HB and AGB stars. In fact, this is what is found here using Ding’s catalogue, as can be seen in Fig. 5b, where Li abundance is shown as a function of metallicity for metallicities between −4.0 and −1.0 corresponding to the Galactic halo and thick-disc region. Here, all three stages (RGB, HB, and AGB stars) attain very large Li abundance values between 4.0 and 5.0 dex, with even a very low metallicity AGB or an upper RGB star exhibiting a Li abundance of 6.15 dex (see below). Concerning the very metal-poor stars in the region between metallicities −4.0 and −3.0, only three RGB stars have been detected and obtained from the literature.

Finally, Fig. 6 presents two Kiel diagrams for all Li-rich giants in this study. These diagrams show log g as a function of Teff, with auxiliary axes displaying Li abundance and metallicity. A particularly noteworthy object is 2MASS J05241392-0336543 with a metallicity of −2.54, which exhibits the highest known Li abundance at 6.15 dex. Kowkabany et al. (2024) noted the challenge of classifying this star as an RGB or AGB star due to its position in the transition region of these evolutionary branches. However, given its low log g value of 1.10 -typical of AGB stars, we can classify it as an AGB star. On the other hand, it can also be an upper RGB star. In this respect, it can be noted that this star presents an important IR excess of 1.60 and that, following our generalised CF mechanism (see Sect. 4), this giant star is currently producing even more fresh Li.

The double sequence observed in the lower part of the Kiel diagram is formed by two distinct stages of the evolutionary path; the red clump (left branch) and the RGB (right branch). The stellar distribution in this diagram is governed by age, metallicity, and, as more recently evidenced, by kinematics when restricting the sample to objects with the same metallicity content (Recio-Blanco et al. 2024). In Fig. 6a, it can be seen that the inner edge of the RGB is populated by the most metal-poor stars. Our classification into HB, RGB, and AGB is based solely on log g.

thumbnail Fig. 3

Spatial distribution of the giant stars used in this work. Here, ωGC is the Galactocentric radius projected onto the Galactic plane and |Z| is the absolute distance from the mid-plane. The radial extent of each stellar class increases as log g decreases. Colours and symbols are the same as in Fig. 1.

thumbnail Fig. 4

Li abundance as a function of Teff. See the main text for details.

thumbnail Fig. 5

Li abundance trends in evolved stars. Panel a (top): general stellar distributions of the catalogues of Ding et al. (2024, blue) and Gao et al. (2021, red), showing Li abundances as a function of log g. The horizontal line at A(Li)=1.5 serves only as a reference, while the vertical line marks the end of the stellar giant branch at log g = 3.5. Panel b (bottom): Li abundance of Li-rich giant stars, RGB (blue), HB (red), and AGB (green), as a function of metallicity ([Fe/H]) in the range −4.0 to −1.0. While RGB stars are present throughout the metallicity range, HB and AGB stars appear only for [Fe/H] > −2.5.

4 The action of the Cameron-Fowler mechanism

The well-known Cameron-Fowler (CF) mechanism (Cameron & Fowler 1971) combines several nuclear reactions that result in the formation of 7Li. It was originally proposed to explain the observed high Li abundances in AGB giant stars with intermediate masses of approximately four or more solar masses. In such stars, the internal stellar layers where 7Be is formed via 3He are relatively close to the external envelope, facilitating the transport of this element to the surface. Once in the envelope, 7Be is transformed into 7Li through the reaction 7Be(e, γ)7Li. This process, also known as the “hot-bottom process”, has been successfully applied by Smith & Lambert (1990).

However, in the more numerous low-mass giant stars, with masses below 2 M, even larger quantities of new Li are produced. This necessitated the identification of an alternative mechanism capable of transporting material to deeper internal layers where 7Be is synthesised. Sackmann & Boothroyd (1999) proposed the so-called “cold-bottom process”, in which an ad hoc conveyor-belt circulation mechanism transports envelope material into the deeper layers of the hydrogen-burning zone, where 7Be reaches its peak internal abundance.

In the literature, it is often assumed that 7Be alone ascends to the surface, where it is converted into 7Li. However, simulations of nuclear transport reactions by Yan et al. (2018) suggest a more accurate picture of these processes. Their models, designed to replicate Li enrichment in a giant star with an exceptionally high Li abundance of 4.7 dex, indicate that both 7Be and 7Li are transported together, as 7Be is continuously converted into 7Li. The rapid upward motion of this Li-rich material is crucial to preventing 7Li destruction by proton reactions during transport. As a result, a new Li-enriched external envelope is formed.

The nuclear simulations by Yan et al. (2018) determined that the required upward transport time for the studied case was 47 years. Based on this timescale, DLR25 estimated an upper velocity for 7Li transport of approximately 470 cm/s, assuming a stellar atmospheric scale height of 10 R. This value is consistent with the framework used by Eggleton et al. (2008) to compare their estimated upward velocity of 2 cm/s for carbon transport with that of 7Li. However, Yan (private communication) later recalculated the 7Li upward velocity using a more appropriate scale height for his model (Yan et al. 2018), finding that the value used in DLR25 was overestimated by a factor of approximately 20. Nevertheless, the revised average velocity still remains about ten times larger than that of carbon transport. This difference in transport velocities explains the observed anti-correlation between Li abundance and the 12C/13C ratio, as initially noted by da Silva et al. (1995).

Based on these nuclear processes, DLR25 proposed a general Li enrichment scenario for low-mass giant stars, in which internal material transport begins in the upper hydrogen-burning zone and extends outward, eventually manifesting as external shells. These external shells, which are observable through significant infrared (IR) excesses, are a consequence of mass loss driven by internal angular momentum evolution. This scenario requires episodic Li enrichment followed by substantial mass-loss events occurring sporadically. The internal mechanism driving this sporadic transport remains unknown, though it has been speculated that magnetic instabilities might play a role.

A crucial implication of this revised perspective on the CF mechanism is its potential connection to IR excesses and mass loss. In other words, detecting an IR excess in a Li-rich giant star may indicate that the star is currently undergoing Li enrichment. This idea was explored in DLR25, which focused on Li-rich giant stars in the thin disc with higher metallicities. In that study, based on 10,535 Li-rich giant stars from the LAMOST-Gaia catalogue (Gao et al. 2019), Li abundances ranged from 1.5 to 4.9 dex. Among these, 196 RGB and 421 clump giants exhibited IR excesses, representing 5.8% of the total Li-rich sample. These findings suggest that these stars are actively enriching their envelopes with Li while simultaneously undergoing episodic mass loss over short timescales of approximately 104 years. Notably, as discussed in DLR25, after this brief period of 7Li enrichment, stars retain their Li for a significantly longer timescale of 107 years in the thin disc.

In Table 2, we present 1703 Li-rich giant stars. Importantly, stars with IR excesses are uniformly distributed in the three evolutionary stages (RGB, HB, and AGB) and within the metallicity range of −2.5 to −1.0. These excesses were identified using WISE data by measuring the difference in WISE colours W1 − W4, where W1 corresponds to 3.4 µm and W4 to 22 µm. The selection criteria followed those of Martell et al. (2021) and DLR25, requiring W1 − W4 ≥ 0.5 and excluding the upper limit flux values and the contaminated images.

Could the CF mechanism also be active at even lower metallicities (−4.0 to −2.5)? While there are three confirmed Li-rich RGB stars in this metallicity range (see Fig. 5b), the extreme scarcity of stars in this regime stands in the way of a robust statistical analysis of IR excess frequency and represents a main caveat. However, if the mechanism is indeed general, it should extend throughout the entire history of the Milky Way.

Figure 7 presents the IR excesses for the three evolutionary stages (RGB, HB, and AGB), revealing values as high as five magnitudes, similar to those observed in the thin disc (DLR25). Since these excesses correspond to significant mass-loss episodes, they contribute to Li enrichment in the interstellar medium of the halo/thick disc.

Concerning this contribution, we have to consider two properties of the mechanisms of Li enrichment. These have been briefly discussed in de la Reza et al. (2015) and especially in DLR25. One is a positive contribution in the sense that, due to the proposed universality of Li production, all (at least for the most numerous low-mass giant stars) contribute to the Li enrichment of the ISM. The other is less positive, in the sense that the process of Li enrichment is very short (∼104 years or less), even with episodes of strong mass losses on the order of 10−7– 10−6 M yr−1. In view of this, proper calculation of the yield of Li must be estimated and formulated for Galactic chemical models, and this is beyond the scope of our work.

In Fig. 7, we present the Li abundances as a function of the IR excesses for an ensemble of giant stars selected based on the availability of W1 and W4 magnitudes with associated errors in the WISE catalogue, as well as their inclusion in the catalogues used in this study. A total of 535 stars were selected, divided into three groups with their respective numbers of objects and colours: AGB (367 green), HB (118 red), and RGB (50 blue). Most AGB stars are located in the first quadrant, exhibiting no IR excess and low Li content. A smaller number of HB and RGB stars show similar behaviour in the first quadrant. The remaining stars in the second quadrant have IR excesses W1 − W4 ≥ 0.5, representing the true near-IR (NIR) physical excesses considered in this work. As mentioned before in the context of our general CF mechanism of Li enrichment, the presence of a star with an IR excess indicates that the star is undergoing an active Li enrichment process episode.

Figure 7 clearly shows the notable presence of three different Li thresholds, each corresponding to the three stages of evolution: for RGB stars (blue) at ∼1.5 dex, for HB stars (red) at ∼0.5 dex, and for AGB stars (green) at approximately −0.5 dex. To our knowledge, the presence of three different Li thresholds that appear in low metallicity is unique. Additionally, there is a general tendency for Li abundance to increase with IR excess, as measured by W1 − W4. This supports our generalised CF mechanism and suggests that Li enrichment is directly related to the total energy required to transport stellar material from the stellar interior to the exterior (see DLR25). In this case, the energy requirements differ somewhat for each stage, with the AGB stage being the least energetic.

Accepting these three different Li thresholds and examining Fig. 7, we obtain the following scenario. First, for AGB stars: those located in the second quadrant are considered AGB Li-rich giants currently being enriched with fresh Li. Those in the first quadrant, which show no IR excess, can also be regarded as Li-rich giants, although in these stars the Li enrichment process has already ceased. Notably, in this case there are two super Li-rich AGB stars with Li abundances larger than 4.0 dex. The same scenario also applies to HB and RGB stars.

If our Li-thresholds are correct, the Li-timescales could be different than that of the thin disc which is around 107 yrs. However, the knowledge of their values requires more detailed quantitative calculations.

thumbnail Fig. 6

Kiel diagram for Li-rich giant stars, showing log g as a function of Teff. Panel a (top): metallicity [Fe/H] shown as the auxiliary axis. Panel b (bottom): Li abundance shown as the auxiliary axis. The position of 2MASS J05241392-0336543, the most Li-rich giant star known (A(Li) = 6.15 dex), is marked as a black square.

Table 2

Properties of the Li-rich stars.

thumbnail Fig. 7

Li abundances of giant stars with IR excesses as a function of the WISE colour index W1 − W4. Blue points correspond to RGB stars, red to HB stars, and green to AGB stars.

5 Stellar rotation in the halo and thick disc

In recent literature, Mucciarelli et al. (2024) reported the lack of stellar rotational velocity data required to carry out studies in the low-metallicity regime of giant stars. To our knowledge, the present work represents one of the first steps in addressing this issue by utilising two recent large data collections: on the one hand, the LAMA LAMOST catalogue (Li et al. 2024) for the v sin i data and, on the other hand, the LAMOST DR9 catalogue (Ding et al. 2024) for the Li abundance data. In the Galactic thin disc, studies on the rotational properties of Li-rich giant stars and their correlation with Li abundances remain unsatisfactory due to several fundamental unresolved processes. Some studies have approached this problem by employing direct atmospheric observations (e.g. Frasca et al. 2022) and stellar spot analysis (Kriskovics et al. 2023). A general issue has emerged, indicating an apparent lack of correlation between these two parameters. The most comprehensive study on this topic so far is that of Deepak et al. (2020), who utilised a large sample of Li-poor and Li-rich giant stars from the GALAH survey, finding an anti-correlation between Li abundance and v sin i for three stellar types: Li-poor, Li-rich, and super Li-rich giants (see their figure 7). Regarding the physical mechanisms underlying this open problem concerning the Li versus v sin i relation, some have been discussed in DLR25, but a broader perspective is provided here. At least three key mechanisms are at play: (a) the transfer of total stellar angular momentum (AM); (b) stellar rotation as a driver of activity, and (c) the influence of rotation on the internal reservoir of 3He, which serves as the source of 7Li.

The first mechanism suggests that the final rotational velocity of the outer stellar envelope depends on how the total stellar AM transfer occurs. Since asteroseismology techniques have revealed that the cores of giant stars rotate slowly (see review by Aerts et al. 2019), a general picture has emerged in which the stellar envelope rotates roughly ten times slower than the core, as opposed to the previously assumed several orders of magnitude. This new paradigm aligns with the mean rotation of normal Li-poor giant stars, which exhibit v sin i values below 5 km s−1. However, this scenario does not apply to giant stars at low metallicities, which exhibit significantly larger v sin i values. This discrepancy presents a challenging problem, as different AM transfer mechanisms are required to explain the rapid rotation observed in these stars.

The second key aspect relates rotation to stellar activity. In general, Li-poor giant stars are relatively inactive, exhibiting low mass loss. In contrast, Li-rich giant stars tend to be more active. Dixon et al. (2020) showed that a subset of quiet, normal giant stars exhibit significant UV excesses, with this activity being correlated with rotation, as observed in dwarf stars. Consequently, rotation in some giant stars emerges as a driver of stellar activity, manifested in UV emission. A recent work by Dixon et al. (2025) extends this relation from solar metallicities down to –1.5. How do Li-rich giant stars fit into this scenario? DLR25 showed that among Li-rich and super Li-rich giant stars, Hubble UV emission lines at ∼2500 Å exhibit a correlation between line intensity and v sin i. This behaviour is interpreted as a consequence of mass transport from the interior, activating the chromosphere as material migrates outward. This Li-activity relation in giant stars has also been studied using chromospheric He I at 10830 Å (Sneden et al. 2022; Mallick et al. 2025).

The third point, concerning the impact of rotation on 3He abundance, is primarily a topic for internal stellar modelling. The internal 3He-rich zone forms during the main-sequence phase and serves as the source of 7Li through nuclear reactions: 3He + (4He, γ) → 7Be and 7Be + (e, γ) → 7Li.

Eggleton et al. (2006, 2008), without considering rotational effects, first explained why 3He production is limited and largely destroyed during the RGB phase, ultimately constraining 7Li overproduction. Later studies (Stancliffe 2009; Lagarde et al. 2011) incorporated thermohaline mixing processes to explain 3He destruction in RGB and AGB low-mass stars.

Although stellar rotation in the thin disc typically reaches maximum observed values around 35 km s−1 (Reddy & Lambert 2005), significantly higher values are observed at very low metallicities. This could be due to the smaller physical size of stars at low metallicities, allowing for faster rotation.

Nevertheless, for lower rotational velocities (v sin i < 40 km s−1), AGB and HB stars can exhibit significantly enhanced Li abundances, reaching values around 5.0 dex. The underlying physical mechanisms governing the overall distribution of Li abundances and their correlation with v sin i, particularly the existence of this plateau, present a challenging problem in the context of angular momentum transport, as outlined in the preceding discussion.

Figure 8 displays the Li abundance as a function of v sin i, where a few giant stars with v sin i below 40 km s−1 reach Li abundances typical of very Li-rich giants. In reality, there are many more giants of this type, as illustrated in Fig 5b. They are not present because the LAMOST catalogue of Li et al. (2024) has not measured their v sin i values.

If we examine Figs. 4, 7, and 8, considering the values of A(Li) as functions of Teff, W1 − W4, and v sin i for the three evolving phases (AGB, HB, and RGB), we can see that in each case, the distributions of A(Li) attain a maximum asymptotic value as their abscissae increase. The only case where the distribution is characterised well by a plateau is the one shown in Fig. 8 for v sin i values greater than 40 km s−1.

To characterise the plateau, we followed the recommendation of Li et al. (2024), considering only those values for which the FLAGS assigned to each physical variable are equal to zero. Specifically, we selected stars with both FLAG_MAD_VSINI = 0 and FLAG_DELTA_VSINI = 0. Our sample exhibits a median of approximately 0.1, with a standard deviation of 0.3. The plateau values corresponding to the three different selections are listed in Table 3. They were derived as the medians of the v sin i > 40 km s−1 distributions. In Fig. 8, these values are shown using the same colour scheme as that adopted for the metal-poor giant classes. The statistical values for this case are presented in Table 3.

The ensemble of Fig. 8 appears to indicate two important conclusions: only slow giant rotators produce high Li abundances, while rapid and very rapid giant rotators produce a limited amount of Li. However, a complete confirmation of this statement requires measurements of the v sin i values of a large part of the remaining very Li-rich giants.

Concerning the second effect mentioned above: that is, Li-rich giant stars as stellar activators. The point here is to show in this figure whether Li-rich giant stars, with Li abundances greater than or equal to 1.5 dex, eventually present indications of activity appropriate for these stars. This can be achieved by means of different known indices such as RHK$R_{{\rm{HK}}}^\prime $, RHα$R_{{{\rm{H}}_\alpha }}^\prime $, RNUV$R_{{\rm{NUV}}}^\prime $, and RFUV$R_{{\rm{FUV}}}^\prime $, which have been applied recently only to stars belonging to the Galactic thin-disc (Han et al. 2024). They could be useful in our case if they were applicable to metallicities lower than −1.0. In particular, a comparison between the emission at far-UV (FUV) produced by the external stellar regions and that near-UV (NUV) with photospheric origin is needed. This task remains to be done for a large number of giant stars in the halo and thick disc and could probably provide better insights into the activity of Li-rich giant stars at very low metallicities.

In the following, we proceed by taking the Li abundance values and the other stellar parameters, such as Teff, log g, and [Fe/H] from LAMOST DR9 (Ding et al. 2024) and the v sin i values from LAMA LAMOST (Li et al. 2024). By selecting giant stars according to our criteria based on log g, as mentioned in Sect. 2, we obtain a collection of 2,468 Li-rich and Li-poor giant stars presented in Table 4. Displaying these stars with their [Fe/H] as a function of the v sin i values, we plot Fig. 9, where, first, for low velocities up to 40 km s−1, the velocities do not change as metallicity decreases. Second, for velocities larger than around 40 km s−1, stars appear to show an increase in their v sin i velocities as metallicity diminishes from approximately −1.0 down to −2.5.with terminal velocities near 90 km s−1. Note that this behaviour corresponds to Li-rich giant stars. One tentative interpretation of this behaviour could be that stars diminish in physical size as their metallicity decreases. The reason for this can be found in the formation of the initial Population II stars with very low metallicities. Dopcke et al. (2011, 2013), using hydrodynamic simulations, found that under those conditions, dust can be very efficient in cooling the gas and provoking the fragmentation of a cloud. These processes result in the formation of stars with very low masses between 0.01 and 1 M, which, as expected, can be small-sized stars; however, no stellar radii are provided in this study. Some Galactic models, such as that proposed by Chiappini et al. (2006), even suggest that at extremely low metallicities, stars of these small sizes could rotate with velocities as high as around 700 km s−1. In any case, in this work, we are presenting a more realistic observational picture of the stellar rotational scenario for the entire Galaxy.

A new vision on the explanation of the high giant rotators and their sizes appears with the recent work by Mosser et al. (2024), which solves the problem of stellar angular momentum for HB giants by conserving it. In this way, the stellar core and its envelope spin in the same manner. For high rotators, this requires small stellar radii. However, all these properties of high-velocity rotators can be tested by measuring the stellar radii of these objects.

thumbnail Fig. 8

Li abundances of giant stars as a function of stellar rotation velocities. The most prominent feature is a plateau for v sin i > 40 km s−1, where no super Li-rich RGB (blue) and HB (red) stars with Li abundances exceeding 3.2 dex are found.

Table 3

Statistical properties of the different stellar classes.

6 Discussion and conclusions

Until now, the stellar evolution of field low-mass Li-rich giant stars at very low metallicities has remained a largely unexplored area of research. We studied the main properties of these sources, which produce fresh 7Li during their advanced evolutionary stages in the Galactic halo and thick disc. Additionally, we explored, for the first time in this Galactic region, the general behaviour of the stellar rotational velocities of both Li-rich and normal Li-poor giant stars.

For Li studies, the metallicities fall within the range of −4.0 to −1.0, whereas for the rotational analysis, the range considered is from −2.5 to −1.0. Two major data sets were used for this purpose: for Li-rich giant stars, the LAMOST DR9 catalogue (Ding et al. 2024), and for the v sin i data of both Li-rich and Li-poor giant stars, the LAMA LAMOST catalogue (Li et al. 2024). One challenge in studying the halo and thick disc is the rarity of these stars in the metallicity range of −4.0 to −3.0, which account for only 0.1% of the stars in the Galaxy (Yao et al. 2024). We summarise the main findings of our study below.

  • The distribution of giant stars in the Galactic phase space: the Toomre diagram in Fig. 1 shows that most of the stars in the sample belong to the halo and thick disc, with only a few candidates likely to be members of the metal-poor thin disc. Based on the data, we obtained the following classifications: halo (74%), thick disc (22%), and thin disc (4%). In Fig. 3, the spatial distribution shows that AGB stars occupy a larger volume, whereas HB and RGB stars exhibit a more concentrated distribution. This structure simply reflects the intrinsic luminosity gradient associated with the evolutionary stage of the giant stars in our sample (see Fig. 4). AGB stars, being the most luminous, are visible at greater distances. A potential (yet undetected) influence on Li enrichment could arise from the differing spatial distributions of the three evolutionary stages considered.

  • Detection of deficient alpha-element giant stars in the halo and thick disc: as observed (Fig. 2) and as expected for the low metallicities characteristic of the halo and thick disc, the [α/Fe] ratio as a function of [Fe/H] is positive and generally exceeds 0.1. However, a few giant stars display negative ratios, indicating a deficiency in these elements. These relatively rare objects, found at very low metallicities, are particularly noteworthy as they suggest early enrichment by Type Ia supernovae as well as by core-collapse supernovae that are deficient in α-elements (Jeena & Banerjee 2024). The presence of such giants across the metallicity range from −2.5 to −1.0 provides a valuable opportunity to investigate the rate and nature of supernova contamination during the evolution of the halo and thick disc.

  • Relation to temperature: in Fig. 4, we can see that all the Li abundances appearing in this work exhibit a clear relation with the important parameter, Teff, which clearly separates the three evolutionary stages: AGB, HB, and AGB.

  • The stellar evolutionary stages of Li-rich giant stars: at extremely low metallicities, these stars resemble fossils of the earliest Population II stars. Even under such conditions, only three Li-rich RGB stars have been identified within the metallicity range of −4.0 to −3.0 (see Fig. 5b). It is noteworthy that these ‘fossil’ RGB Li-rich stars exhibit Li abundances ranging between 2 and 3 dex, indicating that they have undergone Li enrichment through an as-yet unidentified mechanism. We propose that this mechanism corresponds to the well-known Cameron-Fowler nuclear process for 7Li production and that it was already active in the early history of the Galaxy. It is remarkable that the three evolutionary stages (RGB, HB, and AGB) participate in Li production in the halo and thick disc; furthermore, this is also the case in the thin-disc, whereby Li production is maintained by giant stars throughout the entire Galaxy. This is valid even if HB and AGB stars are only detected at metallicities around −2.7 (see Fig. 5b), as these stars exhibit the highest observed Li abundances, spanning to a maximum of 6.15 dex. These evolutionary stages play a role in Li production via episodic, substantial mass loss, enriching the interstellar medium in the halo/thick disc, just as giant stars do in the thin disc.

  • The general validity of the Cameron-Fowler mechanism for 7Li formation across the Galaxy: in DLR25, a general framework for the CF mechanism in the thin disc is presented, detailing the various steps of Li enrichment in giant stars as a result of stellar angular momentum evolution. This includes the transport of 7Be and 7Li from the internal upper H-burning layer to the stellar surface, forming circumstellar shells with short-lived episodes of intense mass loss, observable as IR excess. Given that IR excesses have been detected throughout the metallicity range −2.5 to −1.0, we argue that the CF mechanism is active in this interval. In the extreme low metallicity range of −4.0 to −3.0, only three RGB Li-rich giants have been detected due to the extreme scarcity of Galactic stars in this metallicity region. However, since these few stars exhibit Li enrichment, we infer that the CF mechanism is also at work there. If confirmed, this would imply that the CF mechanism operates universally across the entire Galaxy.

  • Detection of three Li-thresholds: by means of the general CF mechanism and 535 giant stars with good quality WISE data to measure their IR excesses, we found the existence of three Li thresholds corresponding to the three giant evolving phases: for RGB at 1.5 dex, for HB at approximately 0.5 dex, and for AGB at approximately −0.5 dex. The Li formation processes from these thresholds is considered to be independent for each phase. Additionally, they show a tendency to produce more Li as the IR excesses increase (see Fig. 7), indicating a progressive energy requirement for the complete evolution of stellar angular momentum to transport mass from the interior to the external parts of the star, forming fresh 7Li and creating circumstellar shells. These energy requirements appear to progress from AGB to RGB stages. If all of these findings are indeed correct, these triple thresholds would completely change the notion of Li richness in the low metallicity regime. While RGB stars surprisingly maintain the well-known 1.5 dex Li threshold, this is not the case for the HB and AGB stages. In particular, AGB stars with such tiny quantities of Li are characterised as Li-rich, with the majority of them fitting this description.

  • Activity of Li-rich giant stars: while normal Li-poor giant stars are generally quiescent, Li-rich giants are active, with their activity potentially driven especially by rotation. Unfortunately, there is an almost complete absence of published appropriate spectral activity indicators in the low-metallicity regime considered in this work. This impedes any progress in the study of the relation between Li and activity.

  • The presence of a plateau for larger rotation velocities: the behaviour of Li abundances as a function of the rotational velocities (Fig. 8) presents two different scenarios depending on whether v sin i is smaller or larger than 40 km s−1, which appears to be a critical velocity. For smaller values, RGB, HB, and AGB stars exhibit the entire range of Li abundances from ∼−2.0 up to 5.0 dex. This indicates that only low-velocity giant rotators are capable of producing Li-rich and super Li-rich giants. On the contrary, large rotators form a plateau that spans a wide range, encompassing Li abundances from ∼0.5 to ∼2.2 dex, with no stars exhibiting high Li abundances above 3.2 dex. Regarding very rapid rotators, we propose that this behaviour could be explained by a progressive diminishment of the star’s size, allowing them to spin at an increasingly faster rate. Theoretical simulations of the formation of very low-mass stars at very low metallicities support this scenario. This situation is also supported by a recent solution regarding the transfer of stellar angular momentum for HB giants (Mosser et al. 2024), in which large rotators require smaller stellar radii. Nonetheless, all the mentioned properties of high-velocity rotators can be tested by measuring the stellar radii of these objects. The conclusion that only low rotators can produce very Li-rich giants, however, would require studies involving a greater number of observed values of v sin i than the sample presented here.

  • The presence of an increase in rotation velocities of Li-rich giant stars with a decrease in metallicities: when the metallicities of giant stars are represented as a function of the rotational velocities (Fig. 9), again two different scenarios appear for values smaller or larger than the critical 40 km s−1 velocity. For slower giant rotators, there is no change in their velocities as metallicity decreases from approximately −1.0 to −2.5. In contrast, for faster rotators, a mixed group of only RGB and HB stars appears to increase their velocities as metallicity decreases by the same interval. AGB stars also decrease in the same way. The same arguments related to the sizes of the stars, as mentioned before, can be applied here. The necessity to increase the lifetimes of the 3He layers, considering stellar rotations: Early studies by Eggleton et al. (2006, 2008) explain how the 3He reservoir, which is used to create 7Li, is destroyed during the RGB phase, thereby preventing an overproduction of 7Li. Nevertheless, these studies do not account for rotation in their models.

In this work, we present a large sample of RGB and HB Li-rich stars with rotation velocities of up to ∼170 km s−1 (most of them below ∼90 km s−1). Our findings indicate that future internal stellar models considering those stellar rotations must extend the lifetimes of 3He zones where 7Li is created during the advanced stages of evolution.

Table 4

Joint table of stellar parameters from LAMOST and Gaia catalogues.

thumbnail Fig. 9

Metallicity [Fe/H] is shown as a function of the rotational velocity. The branch of stars starting at approximately 40 km s−1 and showing an increase in velocity up to nearly 90 km s−1 as [Fe/H] decreases from around −1.0 to −2.5 is composed mainly of Li-rich RGB and HB stars. Colours and symbols are the same as in Fig. 1.

Data availability

Tables 2 and 4 are available at the CDS via https://cdsarc.cds.unistra.fr/viz-bin/cat/J/A+A/706/A133.

Acknowledgements

We thank the referee for a detailed review and for the insightful comments and suggestions provided. R.d.l.R. wishes to thank H.L. Yan for a calculation included in this paper, and Naomi Snoek and Pacha Guzman Deheza for fruitful conversations. This research has used the Spanish Virtual Observatory (https://svo.cab.inta-csic.es) project funded by MCIN/AEI through grant PID2023-146210NB-I00. F.L.A. also thanks the technical support provided by A. Parras (CAB) and the encouraged support offered by R.M. Castro-Sánchez. This work has been partially funded by the Spanish MCIN/AEI grant PID2022-136640NB-C21. E.J.A. acknowledges financial support from the Severo Ochoa grant CEX2021-001131-S funded by MCIN/AEI/ 10.13039/501100011033. E.J.A. has made continuous use of TopCat (Taylor 2005). This work presents results from the European Space Agency (ESA) space mission’s Gaia data. Gaia data are being processed by the Gaia Data Processing and Analysis Consortium (DPAC). Funding for the DPAC is provided by national institutions, particular those participating in the Gaia MultiLateral Agreement (MLA). The Gaia mission website is https://www.cosmos.esa.int/gaia. The Gaia archive website is https://archives.esac.esa.int/gaia.

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All Tables

Table 1

Comparison of stellar parameters from Ding et al. (2024) and Li et al. (2024) for 2465 common stars.

Table 2

Properties of the Li-rich stars.

Table 3

Statistical properties of the different stellar classes.

Table 4

Joint table of stellar parameters from LAMOST and Gaia catalogues.

All Figures

thumbnail Fig. 1

Diagram of Toomre for the stellar samples used in this work. Green indicates AGB stars, red represents HB stars, and blue corresponds to RGB stars. The two semicircles indicate, as a first approximation, the boundaries between the thin and thick disc (70 km s−1), and between the thick disc and the halo (180 km s−1).

In the text
thumbnail Fig. 2

[α/Fe] versus [Fe/H]. Most of the stars are concentrated around [α/Fe] = 0.23 (median) with a σ = 0.07. Green indicates AGB stars, red represents HB stars, and blue corresponds to RGB stars.

In the text
thumbnail Fig. 3

Spatial distribution of the giant stars used in this work. Here, ωGC is the Galactocentric radius projected onto the Galactic plane and |Z| is the absolute distance from the mid-plane. The radial extent of each stellar class increases as log g decreases. Colours and symbols are the same as in Fig. 1.

In the text
thumbnail Fig. 4

Li abundance as a function of Teff. See the main text for details.

In the text
thumbnail Fig. 5

Li abundance trends in evolved stars. Panel a (top): general stellar distributions of the catalogues of Ding et al. (2024, blue) and Gao et al. (2021, red), showing Li abundances as a function of log g. The horizontal line at A(Li)=1.5 serves only as a reference, while the vertical line marks the end of the stellar giant branch at log g = 3.5. Panel b (bottom): Li abundance of Li-rich giant stars, RGB (blue), HB (red), and AGB (green), as a function of metallicity ([Fe/H]) in the range −4.0 to −1.0. While RGB stars are present throughout the metallicity range, HB and AGB stars appear only for [Fe/H] > −2.5.

In the text
thumbnail Fig. 6

Kiel diagram for Li-rich giant stars, showing log g as a function of Teff. Panel a (top): metallicity [Fe/H] shown as the auxiliary axis. Panel b (bottom): Li abundance shown as the auxiliary axis. The position of 2MASS J05241392-0336543, the most Li-rich giant star known (A(Li) = 6.15 dex), is marked as a black square.

In the text
thumbnail Fig. 7

Li abundances of giant stars with IR excesses as a function of the WISE colour index W1 − W4. Blue points correspond to RGB stars, red to HB stars, and green to AGB stars.

In the text
thumbnail Fig. 8

Li abundances of giant stars as a function of stellar rotation velocities. The most prominent feature is a plateau for v sin i > 40 km s−1, where no super Li-rich RGB (blue) and HB (red) stars with Li abundances exceeding 3.2 dex are found.

In the text
thumbnail Fig. 9

Metallicity [Fe/H] is shown as a function of the rotational velocity. The branch of stars starting at approximately 40 km s−1 and showing an increase in velocity up to nearly 90 km s−1 as [Fe/H] decreases from around −1.0 to −2.5 is composed mainly of Li-rich RGB and HB stars. Colours and symbols are the same as in Fig. 1.

In the text

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