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Table 1

Summary of the computational schemes for S I.

Parity MR-MCDHF MR-RCI AS NCSFs
even 3s23p3np (n = 3 − 8), 3p6, 3s23p3np (n = 3 − 8), 3s23p3nf (n = 4, 6),
3s23p3nf (n = 4, 5), 3p6 3s3p3np7d (n = 3 − 7), 3sp3nf7d (n = 4, 5), 3s23pnp7d2 (n = 3, 4) {12s, 12p, 11d, 10f, 9g, 8h} 11 049 420

odd 3s23p3ns (n = 4 − 7), 3s3p5, 3s23p3n (n = 4 − 8),
3s23p3nd (n = 3 − 7) 3p54s, 3s23p3nd (n = 3 − 7), {12s, 12p, 11d, 10f, 9g, 8h} 8 146 099
3s3p5, 3p54s 3s3p3ns7d (n = 4 − 7), 3sp3nd7d (n = 3 − 7), 3p57d, 3s23p4s7d2, 3s3p4np (n = 4 − 8)

Notes. MR-MCDHF and MR-RCI, respectively, denote the multi-reference sets used in the MCDHF and RCI calculations. AS is the active sets of orbitals. NCSFs are the numbers of generated CSFs in the final RCI calculations.

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