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Table 12

Deuterated vibrational modes of CHD2OH in astrophysical ice mixtures at 10 K in the mid-infrared region.

Mode/cm−1 (μm) Binary mixture H2O matrix CO matrix
CD2 asym. stretch 2180 (4.59) 2181 (4.59) 2180 (4.59)
C−H bend 1329 (7.52) 1330 (7.52) 1329 (7.52)
C−H bend 1304 (7.67) 1305 (7.66) 1304 (7.67)
CD2 bend 1087 (9.20) 1087 (9.20) 1088 (9.19)
CD2 wag 950 (10.53) 950 (10.53) 949 (10.54)
CD2 twist 894 (11.19) 893 (11.20) 893 (11.20)

Notes. Band positions are given in cm−1, with corresponding wavelengths in μm shown in parentheses. Minor shifts of 1–2 cm−1 indicate preservation of deuterated features across different ice matrices.

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