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Table 13

Deuterated vibrational modes of CD3OH in astrophysical ice mixtures at 10 K in the mid-infrared region.

Mode/cm−1 (µm) Binary mixture H2O matrix CO matrix
CD3 sym. stretch 2072 (4.82) 2075 (4.82) 2074 (4.82)
CD3 asym. bend 1068 (9.36) 1069 (9.35) 1070 (9.35)
C − O stretch 982 (10.18) 981 (10.19) 983 (10.17)
CD3 rock 899 (11.12) 903 (11.07) 899 (11.12)

Notes. Band positions are given in cm−1, with corresponding wavelengths in μm shown in parentheses. Minor shifts of 1–3 cm−1indicate preservation of deuterated features across different ice matrices.

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