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Fig. 3

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Model fits of PSO J318 obtained with our fiducial two-column retrieval setup, considering different types of silicate clouds. Panel a shows the best-fit spectrum of the overall winning model (black solid line) plotted on top of the JWST data (gray circles, with 10b error scaling). The winning model assumes amorphous spherical SiO particles. The flux contribution of the two individual columns is also shown, at their best-fit relative scaling (salmon and rose colored lines, respectively). The light blue line shows the result of recalculating the best-fit model, but turning off the cloud opacities. Panel b shows the residuals between the best-fit model and the data (with 10b error scaling). Panel c is a version of Panel a that zooms in on the silicate feature, but the best-fit model is shown in pink instead. Panels d–m show the same zoomed-in view of the silicate feature but for the other tested silicate feature candidates. Panel n shows the residuals between model and data for the various silicate cloud species using the same colors as in panels c–m.

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